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Show Transition Metal Carbonyl Structures Show C-F Bond Lengthening Paul Oh kid, (Thomas Richmond, Atta Arif J Department of Chemistry, University of Utah Tran^rtran rneial* are useful a* catalyst* because of their unique bonding capabilrties. Binding oF^ub straiesio a rneial renter can dramatical hy alter 1 heir chernica I reactivity leading to newY*aysto make and break chernical t^rds. This jungest* 1 hat r>?i rnn My refractory bonck may be articled and could Fdential ^ fwd to new [^ithv^vi "^r ^ hemVal reactions In a ^ratalytr intern urxtef mild conditions The harbor rnono>:ide frjand Mabilizeilowvalent metal c^rtcnv^rnplem? and are often key catalyst prw u i^orH^r a vn rfcgty of tran^Forrnations of organic modules. Our researc h ci ioup i? inwrested in de^lopma new way? of wtrvati ng C F bonds ?i?rneani to re*rt v^i h p^r^teni Huor^rarbon com pcund? found In ihe flnvlronrntnt. Ultimately, we to demise <:atalvst? <rap?bt oF c*e?troving thew othersw Inert modules, ^Ve ?ra exptonng the M i u^tu ial take plwe upon binding oFfluorocnroonoa^d linn nd? to Mnnndfle^arbonyl com pieces, Theexad medu^ncnin!3le^rys1ak ray crystal Ijq iaphy Among these are nlCOIKOCFiCFJ, HnKOJSCFftTF! fielCOJSCOCF5CF9, and we have diwovef ed a sq n ifi^ant lencjthpning oF C F bond? ndjaceni to the rneial which m?v lead to new way? oF breaking nomna In/very &1 rona C F : |