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Show 78 to believe4.however, that the one-electron generally Jones-Eyring terms give a relatively small and Cotton effect associated with reasoning is that in The itions No is It explaino a groups approximation the trans- usually either purely electrically are optical rotation Jones-Eyring moder is then since we a strong electric dipole transitiono isolated the contribution to predicted in the or oe magnetically allowedo electron model and have to go to the first order to bring I in te conjugate transition momento But for electrically allowed transition the coupled oscillator term predicts a nonvanishing rotational strengtho matrix elements of that the first Moreoveri if a mUltipole expansion Equations 2ol6a and non-zero terms of both 2016c is of the used, it is potential found equations have a r: distance J dependency Since the distances between the 0 and the groups of the sugar the 6A chromophoric center moiety are relatively large (4 to r-4 factor would tend to made the two terms small alsoo we present evidence that the contribution It achieve small cn be blamed chromophores and extensive only a small on divergence between theory the many Most of these such as C=O, C=C. approximations were made with and S-H in mindo suggested that the group should be We have as to the and approximations that were made "o chromophores)such as the phenyl group suggestions were made followed 0 that the plausible tractabilityo it has been In Section 0 is very experiment one-electron term makes ). 7 For complex more dealt with subdividedo60 here, No general procedures that could be suggested one possible approach as a research prQPosalo |
