OCR Text |
Show TABLE 1 . REACTION MECHANISM (Cont.) 61 ~ + HO · fiNO + H 2.8fl8E+13 8.fl fl.fl 18 62 ~ + HO · N + H2O 5.flflflE+11 fl.5 2flflfl .fl 18 6' N + HO · NO + H '.8flflE+13 ILfl fl.fl 18 b4 ~2 + HO · N2 + H2O , .flfl0E+13 e .fl fl .fl 23,24 65 ~2 + NO · N2 + HNO 9.1eflE+" 8.fl e.fl 24 66 NO + H02 · N02 + HO '.4flflE+12 fl .e -3flfl.fl 24 67 N02 + H · NO + HO 3.50flE+14 e.fl 15flfl .fl 18,23,24 68 N20 + H · N2 + HO 7. 600E+13 e.0 152fl0.fl 18,2',19 69 ~ + ,., · H + NO + ,., 1.900E+16 fl .0 48700 .fl 24 7fl ~ + HO · NO + H2O 3. 600E+13 e.fl 0.0 18,24 71 tN) + H · H2 + NO 5.flfl0E+12 fl .fl 0.0 18 72 ~ + 0 · CO + N 1.8fl0E+13 e." 0.0 18 7' ~ + 02 a NCO + 0 5.6e0E+12 fl ." fl.fl 18 74 ~ + N02 a NCO + NO '.fl00E+13 fl .fl fl.fl 18 75 ~ + N20 a NCO + N2 1.flfl0E+13 fl .e fl .0 18 76 NCO + 0 a NO + CO 5.6flflE+13 0.e fl.0 18 77 NCO + N a N2 + CO 2.fl00E+13 fl .8 fl .e 18 78 NCO + ,., · N + CO + ,., 3.1eflE+16 -fl .5 48flfl0.fl 18 79 NCO + NO · N20 + CO 1.efl0E+13 fl .fl -4efl .e 18 8e N + CO2 · NO + CO 1. 90flE+1 1 fl.e 34fle.fl 18 81 ~ + H2 · ~ + H '.eeflE+fl5 2.5 22fle.fl 18 82 ~ + HO · ~ + H2O 1.5eeE+13 fl ." 1fl9flfl.fl 18 83 CHN + HO a I-KO+ H 4.8flflE+" fl.fl 11flflfl.e 18 ~ ~ + HO · HOCN + H 4.6fleE+12 fl.fl 15flflfl.fl ** 85 ~ + 0 :: NCO + H 1.4eflE+fl4 2.6 Sflflfl.fl 18 86 ~ + 0 c ~ + CO '.5flflE+fl' 2.6 5flflfl.e 18 87 ~ + HO .: NCO + H 6. flflflE+13 fl .fl fl.e 18 88 NCO + H · ~ + CO 5.efleE+13 fl.fl fl.fl 18 89 NCO + HO · NO + CO + H 1.flfl0E+13 ,,, II 0.e 18 ge NCO + H2 a IKO + H 8.6I1flE+12 8.fl 9flflfl.fl 18 91 Haa. + H · I-KO+ H 1.flflflE+13 11.11 e.t'I 18 92 ~+ H · ~2 + CO 2.flet'lE+13 11.11 3flflfl.t'I 18 93 ~+ 0 & ~ + CO2 '.250E+12 lI.fl 1fl380.fl 29 ~ ~+ HO · NCO + H2O 2.65eE+12 lUI 55421.1' 29 95 0 + S03 '" 02 + S02 8.571£+14 ., . ., -785 .fl 27 96 0 + S02 + ,., & S03 + ,., 5.32.f1E+28 -'.75 5300.fl 27 9 H + S03 '" HO + S02 1.500E+13 11 . 11 fl.e 27 98 HO + S02 + ,., · HS03 + ,., 2.94eE+17 lI .fl e.e 28 99 HS03 + 02 '" S03 + H02 2. "eE+11 11.8 e.e 28 THIRD BODY EFFICIENCIES: REACTI~ 4 fl.flee/H2 fl.eee/H20 fl.fl2lfl/C02 REACTI~ 8 3.3flfl/H2 21.flflfl/H20 5.flflfl/C02 2.flflfl/CO REACTI~ HI 2f1.flflfI/H20 REACTI~ 17 6.flflfl/H20 0.7f1fl/02 REACTI~ 24 1.525/C02 fl.S651N2 REACTI~ 69 2.flflfl/H2 2.21f1fl/02 6.flfl2l/H20 2.fl2IfllN2 footnotes: • k • A . TAb. exp(-EaJRT) A [aJ cm3/(mol.s) Ea [.J cal/mol .. see discussion in text 5 |