OCR Text |
Show TABLE 1 • REACTION MECHANISM No. Reaction A* b* £a* ref . 1 H + 02 · HO + 0 5.1""£+16 -'" 82 16500.0 18 2 H2 + 0 · HO + H 1.800£+10 1." 88"0 ." 18,19,2e 3 H2 + HO · H2O + H 1.2fl,,£+e9 1.3 36ee." 18 4 H + H + M · H2 + M 1."fl"£+18 -1." fl .e 18 5 H + H + H2 · H2 + H2 9.7"0£+16 -0.6 " .e 21 6 H + H + H2O .. H2 + H2O 6.e00£+19 -1.2 0.e 21 7 H + H + CO2 " H2 + CO2 5.500£+20 -2.0 0.0 21 8 H + 02 + M " H02 + M 2.1flfJ£+18 -1.0 0.e 18 9 HO + HO z H2O + 0 6.fl00£+fJ8 1.3 21.21 18 10 HO + H + ,.., " H2O + M 7.500£+23 -2.6 21.0 18 " H02 + H '" H2 + 02 2.5fJfI£+13 fl." 700.21 18,21,19,221 12 H02 + H .. HO + HO 2.500E+14 iL0 1900.0 18,19,20 13 H02 + H · H2O + 0 5.efJ0E+13 e.0 1000.e 20 14 H02 + 0 · HO + 02 4.800E+13 0.0 1000.0 18 15 H02 + HO :a H2O + 02 5.02121£+13 0.0 1000.0 18,19,ZfJ 16 H02 + H02 · H202 + 02 2.fJ00£+12 0." ".f! 18,19,21 17 H202 + M · HO + HO + M 1.290£+33 -4.86 5320f!.0 22 18 H202 + H · H02 + H2 1. 7021£+12 fI.fI 37"fJ .fI 18,21,20 19 H202 + H .. H2O + HO 3. 20f1£+14 fI .fI 89"fI.fl 2.0 2f1 H202 + HO .. H2O + H02 1.flfJfJE+13 fI.fI 18.0.0.21 18,2f1 21 02 + M .. 0 + 0 + M 1. 9f1flE+1 1 e.5 956f1fl .e 18 22 0 + H + M · HO + fit 1.8f1eE+16 e.fl e .fl 21J 23 0 + HO + M z H02 + fit 1.IU'8E+17 fl.8 fl.fl 28 24 CO + 0 + M · CO2 + fit 2.36"E+15 8." H4fl.1J 22 25 CO + 02 " CO2 + 0 2.5e"E+12 8.fl 477"e.8 18,21,221,22 26 CO + HO · CO2 + H 5.466E+flfl 3.14 -497i" fl *it 27 CO + H02 .. CO2 + HO 1.588E+14 fl." 236"fl.fl 21 28 N + NO · N2 + 0 3.38f1E+12 fI.3 fl.8 18 29 N + 02 · NO + 0 6. 48eE+fl9 1.fl 6308.fl 18,19 38 N02 + fit .. NO + 0 + M 1.18flE+16 8.1J 66f1f1f1.fl 18,23,24 31 N02 + 0 · NO + 02 1.eflIJE+13 lJ.fI 6flfl.8 18,23,19,24 32 N20 + M · N2 + 0 + M 1.6f18E+14 fl.fI 516efl.1J 18 " N20 + 0 '" NO + NO 6.92f1E+13 .LfI 266f1fl.fl 23 34 N20 + 0 '" N2 + 02 1.8flflE+14 8.fI 2820f1.fl 18,23 35 NH3 + M · NH2 + H + M 4.88flE+16 fl.fI 939flfl.e 24 36 NH3 + H " r+i2 + H2 7.8e"E+e6 2.4 1fl2"fl.fl 18 37 NHZ + H ,. M-I + HZ 6.9""E+13 fl.fl 360".fI 19 38 Moi2 + ~2 N2 + M-I3 1.flflflE+13 fI .fI .Lfl 24 39 NH2 + M-I .. N2H2 + H 5.fI"flE+13 fI.fI fl." 18 4f1 M-IZ + N :a N2 + H + H 7.2eeE+13 e.fI fI.fJ 18 41 M-I + N .. N2 + H 3. flflflE+13 fl.fI fl.fJ 18 42 M-I + H · N + HZ 3.lJflflE+13 e.fl IU' 18 43 M-I + M-I .. N2 + HZ 3.6eflE+11 fI.6 19f1f1.fl 19 44 M-I + M · N + H + M 3.2flflE+21 -2.fI 834flfl.fl 23 45 1fti2 + M N2 + H + M 2.flflflE+14 fI .fI 3flflflfl.1J 24 46 Ifti2 + H '" N2 + HZ 3. 78flE+13 fl.fl 3flflfl.fl 18 47 N2H2 + M ,. ~ + H + M 5.flflflE+16 fl .fl 5"flflfl.fl 18 48 N2H2 + H c I-M + H2 5.flfleE+13 fl.1J 1flflfl.fl 18 49 MU + 0 · M-t2 + HO 2.1flflE+13 fLfI 9flflfl.fl 18 5fl M-I3 + HO .. M-t2 + H2O 3.3flfJE+12 fl.fl 21flfJ.fl 24 51 NH2 + 0 · 1M + H 6.6flflE+14 -fl.5 fl .fl 18 52 M-I2 + 0 ,. M-I + HO 1.7flflE+13 fl.fl 1fl"0.fl 24 53 NH2 + NO · I-M + HO 6. 1flflE+1 9 -2 .46 187".fl 24 54 NH2 + NO · N2 + H2O 9.1f1flE+19 -2.46 187fJ.fl 24 55 NH2 + 02 OK 1M + HO 5.1flflE+13 fl .fl 3flfl"fI.8 24 56 ~2 + HO ,. Mi + H2O 5.5f1f1E+1fJ fl.7 13flfl .1J 24 57 NH2 + HNO · Mi3 + NO 1.8f1flE+14 fl.fl 18"fl.8 24 58 NH + 02 .. 1M + 0 1.flfJ2IE+13 fl.fl 12flflfJ.fl 18 59 NH + 02 · NO + HO 1.4""E+11 fl .21 20fl8.fl 18 6fl NH + NO · N20 + H 4.3flflE+14 -fl.5 fl.fl 18 4 |