| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Weber, M. E. |
| Title |
Energetics and dynamics in the reaction of Si+ with SiF4. Thermochemistry of SiFx and SiFx+ (x=1,2,3) |
| Date |
1988 |
| Description |
The title reaction is studied using guided ion beam mass spectrometry. Absolute reaction cross sections are measured as a function of kinetic energy from thermal to 40 eV, and three endothermic product channels are observed. The dominant SiF+ + SiF3 channel is only slightly endothermic, while the SiF3+ + SiF and SiF2+ + SiF2 channels have much higher thresholds. The SiF3 + cross section magnitude is about half that of SiF+, while the SiF2+ cross section is an order of magnitude smaller than that of SiF+. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
88 |
| Issue |
11 |
| First Page |
6898 |
| Last Page |
6910 |
| DOI |
10.1063/1.454387 |
| citatation_issn |
219606 |
| Subject |
Silicon fluoride; Ion-molecule reactions; Kinetic energy; Threshold behavior; Endothermic reactions |
| Subject LCSH |
Thermochemistry; Excited state chemistry; Surface chemistry; Potential energy surfaces |
| Language |
eng |
| Bibliographic Citation |
Weber, M. E. & Armentrout, P. B. (1988). Energetics and dynamics in the reaction of Si+ with SiF4. Thermochemistry of SiFx and SiFx+ (x=1, 2, 3). Journal of Chemical Physics, 88(11), 6898-910. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Weber, M. E. & Armentrout, P. B., Journal of Chemical Physics, 88(11), 1988 and may be found at http://dx.doi.org/10.1063/1.454387. |
| Format Medium |
application/pdf |
| Format Extent |
1,529,001 bytes |
| Identifier |
ir-main,7081 |
| ARK |
ark:/87278/s6w673vr |
| Setname |
ir_uspace |
| ID |
702634 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6w673vr |
