Cobalt carbene ion: reactions of Co+ with C2H4, cyclo-C3H6 and cyclo-C2H4O

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Beauchamp, J. L.
Title Cobalt carbene ion: reactions of Co+ with C2H4, cyclo-C3H6 and cyclo-C2H4O
Date 1981
Description An ion beam apparatus is employed to study the formation of the cobalt carbene ion, CoCH2+. This ion is produced in the endothermic reaction of cobalt ions with ethene and cyclopropane and in an exothermic reaction with ethylene oxide. A model is proposed to account for the dependence of experimental cross sections on relative kinetic energy for the endothermic reactions. Using this model to interpret the experimental results, a bond dissociation energy D°(Co+-CH2 ) = 3.7+0.3 eV is derived.
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 74
Issue 5
First Page 2819
Last Page 2826
DOI 10.1063/1.441453
citatation_issn 219606
Subject Cobalt carbine; Ion beam; Bond dissociation energy; Reaction cross section; Endothermic reactions
Subject LCSH Ion bombardment; Carbenes; Transition metal compounds
Language eng
Bibliographic Citation Armentrout, P. B. & Beauchamp, J. L. (1981). Cobalt carbene ion: reactions of Co+ with C2H4, cyclo-C3H6 and cyclo-C2H4O. Journal of Chemical Physics, 74(5), 2819-26.
Rights Management (c)American Institute of Physics. The following article appeared in Armentrout, P. B. & Beauchamp, J. L., Journal of Chemical Physics, 74(5), 1981 and may be found at http://dx.doi.org/10.1063/1.441453.
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Format Extent 765,542 bytes
Identifier ir-main,7035
ARK ark:/87278/s6t7323p
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 707472
Reference URL https://collections.lib.utah.edu/ark:/87278/s6t7323p