| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Liu, Fuyi; Li, Feng-Xia |
| Title |
Guided ion-beam studies of the reactions of Con + (n=2-20) with O2: cobalt cluster-oxide and -dioxide bond energies |
| Date |
2005 |
| Description |
The kinetic-energy dependence for the reactions of Con + (n=2-20) with O2 is measured as a function of kinetic energy over a range of 0 to 10 eV in a guided ion-beam tandem mass spectrometer. A variety of Com+ , ComO+, and ComO2 + (m<n) product ions is observed, with the dioxide cluster ions dominating the products for all larger clusters. Reaction efficiencies of Con+ cations with O2 are near unity for all but the dimer. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
123 |
| Issue |
6 |
| First Page |
64304 |
| Last Page |
15 |
| DOI |
10.1063/1.1998836 |
| citatation_issn |
219606 |
| Subject |
Metal clusters; Cobalt ions; Collision-induced dissociation; Bond energies; Exothermic reactions; Endothermic reactions |
| Subject LCSH |
Dissociation; Thermochemistry; Excited state chemistry |
| Language |
eng |
| Bibliographic Citation |
Liu, F., Li, F.-X., & Armentrout, P. B. (2005). Guided ion-beam studies of the reactions of Con+ (n=2-20) with O2: cobalt cluster-oxide and -dioxide bond energies. Journal of Chemical Physics, 123(6), 1-15. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Liu, F., Li, F.-X., & Armentrout, P. B., Journal of Chemical Physics, 123(6), 2005 and may be found at http://dx.doi.org/10.1063/1.1998836 |
| Format Medium |
application/pdf |
| Format Extent |
54,772 bytes |
| Identifier |
ir-main,7980 |
| ARK |
ark:/87278/s6sb4q26 |
| Setname |
ir_uspace |
| ID |
704183 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6sb4q26 |
