Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Miller, Joel Steven |
Other Author |
Eldridge, J. E.; Fortier, Normand; Bates, Frances E. |
Title |
Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ) |
Date |
1983 |
Description |
We present the powder absorption spectrum of (TMA)(I)(TCNQ) in the far-infrared as a function of temperature. Below 160 K new absorption features appear and others increase in intensity. This behaviour supports the electron- neutron-diffraction evidence of a distortion on the TCNQ chains below the first phase-transition temperature. Effects due to the second phase transition at 89 K are also observed. The results of a group-theoretical analysis are presented. These show that totally-symmetric internal modes ag are to be expected in the infrared spectra of this compound even in the undistorted phase. |
Type |
Text |
Publisher |
National Research Council Canada Research Press |
Volume |
61 |
Issue |
9 |
First Page |
1271 |
Last Page |
1277 |
Subject |
Conductivity, Crystals, Electrons |
Language |
eng |
Bibliographic Citation |
Eldridge, J. E., Fortier, N., Bates, F. E., & Miller, J. S. (1983). Far-infrared powder spectrum of (N(CH3)3D)(I)(TCNQ). Canadian Journal of Physics, 61(9), 1271-7. |
Rights Management |
(c) National Research Council Canada Research Press |
Format Medium |
application/pdf |
Format Extent |
3,374,505 bytes |
Identifier |
ir-main,5276 |
ARK |
ark:/87278/s6pr8dh1 |
Setname |
ir_uspace |
ID |
706438 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6pr8dh1 |