| Publication Type |
journal article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Miller, Joel Steven |
| Other Author |
Sugiura, Ken-ichi; Ushiroda, Kantaro; Johnson, Mitchell T.; Sakata, Yoshiteru |
| Title |
Ferrimagnetic ordering of a methylthio-substituted planar porphyrin based electron transfer salt, octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(III) tetracyanoethanide |
| Date |
2000 |
| Description |
The direct redox reaction between tetracyanoethylene (TCNE) and a planar porphyrinatomanganese(II), octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(II), MnIIOMTP, produced a polymeric electron transfer salt (ETS), that has been structurally and magnetically characterized. The ETS belongs to the orthorhombic Cmca space group. The ETS has an extended one-dimensional linear chain coordination polymer motif comprised of S=2 [MnIIIOMTP]+ and bridging S=1/2 [TCNE]-. with an Mn-NTCNE distance of 2.330(5) A, and lacks solvent. |
| Type |
Text |
| Publisher |
Royal Society of Chemistry |
| Volume |
10 |
| First Page |
2507 |
| Last Page |
2514 |
| Subject |
Magnetic; Temperature; Coupling |
| Language |
eng |
| Bibliographic Citation |
Sugiura, K., Ushiroda, K., Johnson, M. T., Miller, J. S., & Sakata, Y. (2000). Ferrimagnetic ordering of a methylthio-substituted planar porphyrin based electron transfer salt, octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(III) tetracyanoethanide. Journal of Materials Chemistry, 10, 2507-14. |
| Rights Management |
©Royal Society of Chemistry |
| Format Medium |
application/pdf |
| Format Extent |
220,979 bytes |
| Identifier |
ir-main,5424 |
| ARK |
ark:/87278/s6bc4h1k |
| Setname |
ir_uspace |
| ID |
705871 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6bc4h1k |
