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Creator | Title | Description | Subject | Date |
101 |
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Miller, Joel Steven | Structural and magnetic characterization of a- and B-2,4-hexadiyne-1,6-diyl Bis(2,2,5,5-tetramethyl-1-oxyl-3-pyrroline-3-carboxylate) and its thermal degradation product | The search for ferromagnetic organic compounds and polymers is the focus of contemporary research.1 - 5 Polymerization of di-iminoxyl diacetylene monomers has been suggested as a means to prepare a high spin potentially ferromagnetically coupled polymers3 and the thermal, photochemical, and glow di... | Ferromagnetic; Magnetization; Polymers | 1989 |
102 |
|
Armentrout, Peter B. | Guided ion beam study of collision-induced dissociation dynamics: integral and differential cross sections | The low energy collision-induced dissociation (CID) of Cr(CO)6+ with Xe is investigated using a recently modified guided ion beam tandem mass spectrometer, in the energy range from 0 to 5 eV in the center-of-mass (CM) frame. The additions to the instrument, updated with a double octopole system, and... | Collision-induced dissociation; Bond energies; Chromium carbonyl; Xenon | 2001 |
103 |
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Morse, Michael David | Spectroscopic studies of jet-cooled AINi | Resonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the p... | | 1993 |
104 |
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Miller, Joel Steven | 1H NMR investigation of the magnetic spin configuration in the molecule-based ferrimagnet [MnTFPP][TCNE] | 1H NMR line-shape measurements have been performed in the linear chain molecule-based ferrimagnet [MnTFPP][TCNE].xPhMe (TFPP=tetrakis(4-fluorophenyl)porphinato; TCNE=tetracyanoethylene) as a function of temperature. Hyperfine shifts of opposite sign were observed indicating the presence of two oppo... | Magnetization; Magnets; Paramagnetic | 2002 |
105 |
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Morse, Michael David | Electronic structure of the 4d transition metal carbides: dispersed fluorescence spectroscopy of MoC, RuC, and PdC | Dispersed fluorescence studies of the diatomic molecules MoC, RuC, and PdC are reported. New states identified in MoC and RuC are the [...]2?112?1, 3,1?2 states and the [...]2? 312?1, 1?2 state, respectively. Five states re observed by dispersed fluorescence in PdC. The ground state is found to be [... | | 2001 |
106 |
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Miller, Joel Steven | Structure and magnetic properties of MnII[N(CN)2]2(pyrazine). An antiferromagnet with an interpenetrating 3-D network structure | Mn[N(CN)2]2(pyz) (pyz = pyrazine) orders antiferromagnetically at low temperature and possesses intralayer u-NCNCN and interlayer u-pyz ligands that form a pseudo-ReO3 interpenetrating network structure. | Dicyanamide; Polydentate; Temperature | 1998 |
107 |
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Miller, Joel Steven | Structure and magnetic properties of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano 2,5-dimethyl-p-quinodimethanide with a 2.3 K Tc. The first example of cis-coordination of a tetracyano-p-quinodimethanide | The crystal structure of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano-2,5-dimethyl-p-quinodimethanide, [MnTMesP][DMTCNQ]-2p-C6H4Me2 provides the first example of a cis-1,2-u-coordination motif having an infinite zigzag chain structure. [MnTMesP][DMTCNQ]-2p-C6H4Me... | Magnets; Interactions; Coupling | 2000 |
108 |
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Miller, Joel Steven | [Et4N]2[TCNE]2 (TCNE = tetracyanoethylene) - an example of an exceptionally long 2.827 Ã CC bond | Interest in organic compounds exhibiting unusually long CC bonds has been the subject of several recent studies.1-3 The longest sp3-sp3 C-C single bond reported to date is 1.73 A°,1,2 whereas several [TCNE]22- (TCNE = tetracyanoethylene) dimers have been recently reported to form cation-assisted, l... | Synthesis; Crystal; Solution | 2001 |
109 |
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Armentrout, Peter B. | Guided ion beam and theoretical studies of the reaction of Ag+ with CS2: gas-phase thermochemistry of AgS+ and AgCS+ and insight into spin-forbidden reactions | The gas-phase reactivity of the atomic transition metal cation, Ag+, with CS2 is investigated using guided-ion beam mass spectrometry. Endothermic reactions forming AgS+ and AgCS+ are observed but are quite inefficient. This observation is largely attributed to the stability of the closed shell Ag+(... | | 2010 |
110 |
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Miller, Joel Steven; Epstein, Arthur J. | Organic and molecular ferromagnets | Unlike common ferromagnets such as iron, nickel, cobalt or even cobalt-samarium and Nb-Fe-B, it is extremely rare for a discrete molecule, especially an organic or polymeric material, to have cooperative magnetic interactions. Since the mid-1980s a few such materials have been prepared which demon... | Magnetic; Magnetization; Temperature | 1992 |
111 |
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Morse, Michael David | Spectrosopic studies of jet-cooled NiAu and PtCu | Spectroscopic investigations of NiAu and PtCu have revealed that both molecules possess 2?5/2 ground electronic states, and are in this respect analogous to the isovalent molecule NiCu. The ground-state bond lengths (r?) have been measured as 2.351?0.001 ? and 2.335?0.001 ? for NiAu and PtCu, respe... | | 1992 |
112 |
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Morse, Michael David | Predissociation lifetimes of vibrational levels of the excited ? B? (Ka=O) electronic states of Cd ? H? and Cd ? D? complexes | The experimental rates of predissociation of vibrational levels of the ?B? (K'a-O) excited states of the Cd ? HZ and Cd ? D2 complexes are shown to be consistent with both semiclassical and quantum-mechanical pseudodiatomic theoretical treatments of the process. The ?B? pseudodiatomic potential was ... | | 1992 |
113 |
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Morse, Michael David | Rotationally resolved spectra of jet-cooled RuSi | We report the first gas-phase spectroscopic investigation of diatomic ruthenium silicide (RuSi). The molecules were produced by laser ablation of a Ru disk into a flow of helium carrier gas containing 0.5% SiH4, and were cooled in a supersonic expansion. The RuSi molecules were then studied using re... | | 2007 |
114 |
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Miller, Joel Steven; Epstein, Arthur J. | Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited) | A new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-l-oxy) butadiyne has been prepared and characterized by x-ray diffraction, infrared and Raman spectroscopies, and magnetic susceptibility. Unlike t h e Pccn-a phase, the B phase belongs to the Pca2y1 space group [a = 14.265(1) A(o),b ... | Molecular; Magnetic; Thermal | 1988 |
115 |
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Morse, Michael David | Spectroscopic analysis of jet-cooled AICu | Diatomic AlCu has been interrogated using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown to be X l?+, deriving from the 3&3dgd configuration, in agreement with theoretical predictions. The closed-shell nature of this molecule results in a l... | | 1993 |
116 |
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Morse, Michael David | Resonant two-photon ionization spectroscopy of jet-cooled tantalum carbide, TaC | The optical spectrum of diatomic TaC has been investigated for the first time, with transitions recorded in the range from 17 850 to 20 000 cm?1. Six bands were rotationally resolved and analyzed to obtain ground and excited state parameters, including band origins, upper and lower state rotational... | | 2010 |
117 |
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Miller, Joel Steven | Interpenetrating three-dimensional rutile-like frameworks. Crystal structure and magnetic properties of MnII[C(CN)3]2 | The interpenetrating double-density rutile-like structure and magnetic properties of MnII[C(CN)3]2 are determined. | Spin; Bond; Coupling | 1998 |
118 |
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Miller, Joel Steven | Noncollinear antiferromagnetic structure of the molecule-based magnet Mn[N(CN)2]2 | The crystallographic and magnetic properties of the Mn[N(CN)2]2 compound have been investigated by dc magnetization, ac susceptibility, specific heat, and zero-field neutron diffraction on polycrystalline samples. The magnetic structure consists of two sublattices which are antiferromagnetically cou... | Spin; Crystal; Magnetic | 2000 |
119 |
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Morse, Michael David | Rydberg and pulsed field ionization-zero electron kinetic energy spectra of YO | A spectroscopic study of the Rydberg states of YO accessed from particular rotational levels of the A 2II1/2, v=0 state has been combined with a pulsed field ionization, zero electron kinetic energy (PFI-ZEKE) investigation. The results provide accurate values of the ionization energy of YO, ioniz... | | 1999 |
120 |
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Armentrout, Peter B. | Collision-induced dissociation of Fen+ (n=2-10) with Xe: ionic and neutral iron binding energies | Cross sections for collision-induced dissociation (CID) of Fen+ with Xe, 2≤n≤10, are presented. Experiments were performed on a newly constructed guided ion beam mass spectrometer, the design and capabilities of which are described in detail. The single mechanism for dissociation of iron cluster... | | 1989 |
121 |
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Armentrout, Peter B. | Reactions of Ar+, Ne+, and He+ with SiF4 from thermal energy to 50 eV c.m. | Guided ion-beam techniques are used to measure the cross sections for reaction of SiF4 with Ar+, Ne+, and He+ from thermal to 50 eV. Charge transfer followed by loss of F atoms are the sole processes observed. All SiFx + (x = 0-4) products are observed, except for SiF4 + from reaction with Ne+ and ... | Ion-molecule reactions; Tetrafluorosilane; Rare gas ions; Endothermic reactions; Plasma systems | 1989 |
122 |
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Morse, Michael David | Electronic spectroscopy and electronic structure of diatomic CrC | Optical spectra of jet-cooled diatomic CrC have been recorded in the near infrared region using resonant two-photon ionization spectroscopy combined with mass-selective detection of the resulting ions. Several weak transitions have been observed, along with one relatively strong band near 842 nm. Ro... | | 2010 |
123 |
|
Morse, Michael David | Optical spectroscopy of RuC: 18 000-24 000 cm ?1 | The optical spectrum of diatomic RuC has been recorded from 17 800 to 24 200 cm-1. Three previously unidentified excited electronic states were analyzed and identified as having ?'=0, ?'=2, and V853. The ?'=3 state was determined to be a 3?3 state that is suggested to arise from a mixture of the 10?... | | 2004 |
124 |
|
Morse, Michael David | Resonant two-photon ionization spectroscopy of jet-cooled Pt? | The gas phase optical spectrum of jet-cooled Pt? has been investigated over the range of 11 300 to 26 300 cm -1 using resonant two-photon ionization spectroscopy in combination with time-of-flight mass spectrometry. Numerous vibronic bands are observed. Analysis of the data gives the location of som... | | 1988 |
125 |
|
Armentrout, Peter B. | Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energies | The kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form... | Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions | 1998 |