Creator | Title | Description | Subject | Date | ||
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1 |
![]() | Miller, Joel Steven | Magnetically ordered molecule-based assemblies | The development of molecules and assemblies of molecules exhibiting technologically important bulk properties, such as magnetic ordering, is an important worldwide research focus. Organic- and molecule-based magnets have been discovered and several families have been reported with magnetic orderin... | Organic-based; Lattices; Magnets | 2006 |
2 |
![]() | Miller, Joel Steven; Epstein, Arthur J. | Forthcoming attractions | Magnets made from molecules and ions having spins in p orbitals have only been discovered in the past decade. Their solubility in organic solvents and room temperature manufacture means that they should find a variety of applications. | Electron; Temperature; Magnets | 1994 |
3 |
![]() | Miller, Joel Steven | Structure and magnetic properties of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano 2,5-dimethyl-p-quinodimethanide with a 2.3 K Tc. The first example of cis-coordination of a tetracyano-p-quinodimethanide | The crystal structure of meso-tetrakis(2,4,6-trimethylphenyl)porphyrinatomanganese(III) 7,7,8,8-tetracyano-2,5-dimethyl-p-quinodimethanide, [MnTMesP][DMTCNQ]-2p-C6H4Me2 provides the first example of a cis-1,2-u-coordination motif having an infinite zigzag chain structure. [MnTMesP][DMTCNQ]-2p-C6H4Me... | Magnets; Interactions; Coupling | 2000 |
4 |
![]() | Miller, Joel Steven | Isolation and structural determination of octacyanobutanediide, [C4(CN)8]2-; precursors to M(TCNE)x magnets(**) | The reaction of MI2.xMe3CN (M = Mn, Fe) and TCNE (tetracyanoethylene) leads to unprecedented [C4(CN)8]2-U4-metal complexes which have been crystallographically characterized and are precursors to M(TCNE)x-yS magnets. | Absorptions; Magnets; Bond | 1998 |
5 |
![]() | Miller, Joel Steven | Structure, optical and magnetic behaviour of meso-tetraphenyl-porphyrinatoiron(III) tetracyanoethenide, [FeIII(TPP)]+[TCNE].-* | The direct redox reaction between tetracyanoethylene (TCNE) and meso-tetraphenylporphyrinatoiron(II), [FeII(TPP)], formed the electron transfer salt (ETS) [FeIII(TPP)][TCNE], which has been structurally, spectroscopically, and magnetically characterized. It has an extended one-dimensional linear ch... | Magnets; Spin; Electron | 2001 |
6 |
![]() | Miller, Joel Steven | 1H NMR investigation of the magnetic spin configuration in the molecule-based ferrimagnet [MnTFPP][TCNE] | 1H NMR line-shape measurements have been performed in the linear chain molecule-based ferrimagnet [MnTFPP][TCNE].xPhMe (TFPP=tetrakis(4-fluorophenyl)porphinato; TCNE=tetracyanoethylene) as a function of temperature. Hyperfine shifts of opposite sign were observed indicating the presence of two oppo... | Magnetization; Magnets; Paramagnetic | 2002 |