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 | Armentrout, Peter B. | Kinetic energy dependence of association reactions. A new thermokinetic method for large systems | The reactions of bare alkali metal ions (M+5Li+, Na+, or K+) with dimethoxyethane (CH3OCH2CH2OCH3 , (DXE) are studied using guided ion beam tandem mass spectrometry. The bimolecular reaction forms an associative M1(DXE) complex that is long-lived and dissociates back to the reactants. The kinetic en... | Collision-induced dissociation; Association reactions; Bond energies; Dimethoxyethane; Alkali metal ions | 2003 |
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 | Armentrout, Peter B. | Reaction of Cu+ with dimethoxyethane: competition between association and multiple dissociation channels | The reaction of Cu1 with dimethoxyethane (DXE) is studied using kinetic-energy dependent guided ion beam mass spectrometry. The bimolecular reaction forms an associative Cu1(DXE) complex that is long-lived and dissociates into several competitive channels: C4H9O2 11CuH, Cu1(C3H6O)1CH3OH, back to rea... | Dimethoxyethane; Copper ions; Association reactions; Collision-induced dissociation; Phase state theory | 2004 |