Creator | Title | Description | Subject | Date | ||
---|---|---|---|---|---|---|
1 |
![]() | Miller, Joel Steven | Collinear ferromagnetism and spin orientation in the molecule-based magnets M[N(CN)2]2 (M=Co,Ni) | Zero-field unpolarized neutron powder diffraction has been used to study the low-T magnetic structure and T-dependent crystal structure of M[N(CN)2]2 (M=Co,Ni). Both compounds show collinear ferromagnetism with spin orientation along the c axis. The results provide the determination of a complete ma... | Magnetic; Diffraction; Structure | 1999 |
2 |
![]() | Miller, Joel Steven | Decamethylnickelocenium hydrogen-7,7,8,8-tetracyanoperfluoro-p-quinodimethandiide: isolation of the protonated weak base [HTCNQF4]- | Unprecedently stable hydrogen-7,7,8,8- tetracyanoperfluoro-p-quinodimethandiide, [HTCNQF4]-, is isolated and crystallographically characterized. | Structure; Electron; Transfer | 1996 |
3 |
![]() | Miller, Joel Steven; Epstein, Arthur J. | Local structural order in the disordered vanadium tetracyanoethylene room-temperature molecule-based magnet | We determined the vanadium oxidation state and local coordination environment in disordered samples of magnetic V[TCNE]x(x=2) prepared by chemical vapor deposition (CVD). Systematic studies of the x-ray absorption near-edge structure (XANES) in this material and reference compounds show that V ions ... | Magnetic; Solvent; Structure | 2004 |
4 |
![]() | Miller, Joel Steven | Preparation and characterization of square-planar tetrakis(cyanoacetylide) complexes: [MII(C=C-C=N)4]2- (M = Ni,Pd, Pt) | Complexes [MII(C=C-=N)4]2 - (M = Ni, Pd, Pt) are prepared for the first time and the structure of [NEt4]2[Ni(C=C-C=N)4] is determined to have a square-planar geometry | Bonding; Structure; Ligand | 1996 |