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CreatorTitleDescriptionSubjectDate
1 Armentrout, Peter B.Reactions of Pt+ with H2, D2, and HD: effect of lanthanide contraction on reactivity and thermochemistryA guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cation, Pt1, with molecular hydrogen and its isotopologs. A flow tube ion source produces Pt1 ions in its electronic ground state term and primarily in the lowes...Metal clusters; Platinum ions; Lanthanide contraction; Bond energies; Endothermic reactions; Transition metal ions; Dihydrogen2002
2 Armentrout, Peter B.Reactions of Ta+ and W+ with H2, D2, and HD: effect of lanthanide contraction and spin-orbit interactions on reactivity and thermochemistryA guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cations, Ta1, and W1, with molecular hydrogen and its isotopologs. A flow tube ion source produces Ta1 and W1 ions in their electronic ground state term and p...Metal clusters; Tantalum ions; Tungsten ions; Lanthanide contraction; Bond energies; Endothermic reactions; Transition metal ions; Dihydrogen2002
3 Armentrout, Peter B.Reactions of Ta+, W+, and Pt+ with H2, D2, and HD: effect of lanthanide contraction and spin-orbit interactions on reactivity and thermochemistryThere have been extensive experimental studies of the reactions of atomic first-row and second-row transition metal cations with dihydrogen and its isotopic analogues in our group. For third-row transition metal cations, however, only La+ and Lu+ systems have been studied experimentally although t...Lanthanide contraction; Spin-Orbit interactions; Reactivity2002
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