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1 Miller, Joel StevenCharacterization of novel TCNQ and TCNE 1 : 1 and 1 : 2 salts of the tetrakis(dimethyamino) ethylene dication, [{(CH3)2N}2C-C{N(CH3)2}2]2+Addition of TCNQ to a solution of tetrakis(dimethylamino)ethylene in MeCN produces the salt [TDAE][TCNQ]2; the dipositive cation, [{(CH3)2N}2C-C{N(CH3)2}2]2+, is nonplanar, with a dihedral angle of 63.9(o), while the TCNQ anions crystallize as [TCNQ]2 2- dimers with an interplanar separation of 3.1...Electron; Oxidations; Transfer1996
2 Miller, Joel StevenCharge transfer complexes of 2,4,6-tricyano-s-triazine with tetrathiafulvalene (TTF) and N,N,N' ,N'-tetramethyl-p-phenylenediamine (TMPD)Reaction of 2,4,6-tricyano-s-triazine (TCT) with tetrathiafulvalene (TTF) and N,N,N',N'-tetramethylp-phenylenediamine (TMPD) leads to 1 : 1 charge transfer complexes. The crystal structures of the TTF[TCT], as well as the decomposition product due to hydrolysis of the [TMPD][TCT], i.e. HTMPD]+[2,4-d...Electron; Solution; Hydrolysis2002
3 Miller, Joel StevenDecamethylnickelocenium hydrogen-7,7,8,8-tetracyanoperfluoro-p-quinodimethandiide: isolation of the protonated weak base [HTCNQF4]-Unprecedently stable hydrogen-7,7,8,8- tetracyanoperfluoro-p-quinodimethandiide, [HTCNQF4]-, is isolated and crystallographically characterized.Structure; Electron; Transfer1996
4 Miller, Joel Steven; Epstein, Arthur J.Forthcoming attractionsMagnets made from molecules and ions having spins in p orbitals have only been discovered in the past decade. Their solubility in organic solvents and room temperature manufacture means that they should find a variety of applications.Electron; Temperature; Magnets1994
5 Miller, Joel StevenNovel coordination of dicyanamide, [N(CN)2]-: preferential binding of the amide nitrogenCoII[N(CN)2]2(H2BiIm)2, 1, and {CoII[N(CN)2](H- 2BiIm)2}Cl, 2 (H2BiIm = 2,2'-biimidazole) have been structurally, spectroscopically, and magnetically characterized with both containing dicyanamides bound in unprecedented manners; namely, solely via the amide nitrogen for 1, and via an imide N form...Magnetic; Dicyanamide; Electron2002
6 Miller, Joel StevenOn the existence of long C-C bonds between pairs of anions which repel: when and why? A test case on the [TCNE]22- dimers found in ionic crystals*Many of the Cm[TCNE]n (C = cation) salts have intradimer C-C interactions in the range of 2.9 to 3.5 A(°) and show the electronic fingerprints associated with C-C bond formation (IR and UV spectra, magnetic properties, structural changes), despite the fact that two [TCNE].- anions should repel each...Electron; Spectroscopic; Salts2002
7 Miller, Joel Steven; Epstein, Arthur J.Optical properties of quinolinium tetracyanoquinodimethanide, [Qn(TCNQ)2] and (N-methylphenazinium)x(phenazine)1-x (tetracyanoquinodimethane) [(NMP)x(Phen)1-x(TCNQ)]We present here optical-absorption data of quinolinium ditetracyanoquinodimethanide [Qn(TCNQ)2] and (N-methylphenazinium)x(phenazine)1-x(tetracyanoquinodimethanide) [(NMP)x(Phen)1-x(TCNQ)] for 0.5 <_x<_ 0.6. These materials span the range of electronic structure from commensurate, to commensurate ...Commensurate; Lattice; Electron1989
8 Miller, Joel StevenStructure, optical and magnetic behaviour of meso-tetraphenyl-porphyrinatoiron(III) tetracyanoethenide, [FeIII(TPP)]+[TCNE].-*The direct redox reaction between tetracyanoethylene (TCNE) and meso-tetraphenylporphyrinatoiron(II), [FeII(TPP)], formed the electron transfer salt (ETS) [FeIII(TPP)][TCNE], which has been structurally, spectroscopically, and magnetically characterized. It has an extended one-dimensional linear ch...Magnets; Spin; Electron2001
9 Mattis, Daniel C.What is the effective mass of an exciton?In the effective-mass approximation, the mass M* of an exciton is just the sum of the electron and hole masses, me*+ mh*. However, the effective-mass approximation is invalid if the forces are strong. Here we derive a plausible formula for the n th bound state of the exciton: Mn*= (me* + mh*) / (...Kinetic; Energy; Electron1984
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