TO
1 - 25 of 3
| Creator | Title | Description | Subject | Date | ||
|---|---|---|---|---|---|---|
| 1 |
 | Armentrout, Peter B. | Guided ion-beam studies of the kinetic-energy-dependent reactions of Con+ (n=2-16) with D2: cobalt cluster-deuteride bond energies | The kinetic-energy-dependent cross sections for the reactions of Con + (n=2-16) with D2 are measured as a function of kinetic energy over a range of 0-8 eV in a guided ion-beam tandem mass spectrometer. The observed products are ConD+ for all clusters and ConD2+ for n=4,5,9-16. | Cobalt ions; Metal clusters; Deuteride; Collision-induced dissociation; Endothermic reactions; Bond energies | 2005 |
| 2 |
 | Armentrout, Peter B. | Guided ion-beam studies of the reactions of Con + (n=2-20) with O2: cobalt cluster-oxide and -dioxide bond energies | The kinetic-energy dependence for the reactions of Con + (n=2-20) with O2 is measured as a function of kinetic energy over a range of 0 to 10 eV in a guided ion-beam tandem mass spectrometer. A variety of Com+ , ComO+, and ComO2 + (m<n) product ions is observed, with the dioxide cluster ions domina... | Metal clusters; Cobalt ions; Collision-induced dissociation; Bond energies; Exothermic reactions; Endothermic reactions | 2005 |
| 3 |
 | Armentrout, Peter B. | Methane activation by cobalt cluster cations, Con+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexes | The kinetic energy dependences of the reactions of Con + (n=2-16) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. The main products are hydride formation, ConD+, dehydrogenation to form ConCD2 +, and double dehydrogenation yielding ConC+. | Cobalt ions; Transition metal ions; Bond energies; Endothermic reactions; Dehydrogenation; Deuterated methane | 2009 |
1 - 25 of 3