Creator | Title | Description | Subject | Date | ||
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1 |
![]() | Lupton, John Mark | Linewidth-limited energy transfer in single conjugated polymer molecules | Using low temperature single molecule spectroscopy on rigid-rod conjugated polymers we are able to identify homogeneously broadened, strongly polarized emission from individual chromophore units on a single chain. Gated fluorescence spectroscopy allows real time imaging of intramolecular energy tran... | Linewidth-limited; Energy transfer; Rigid-rod; Single molecule spectroscopy; Gated fluorescence spectroscopy; Chromophores; Intramolecular energy transfer; Spectral linewidth | 2003-12 |
2 |
![]() | Lupton, John Mark | Ultrafast intramolecular energy transfer in single conjugated polymer chains probed by polarized single chromophore spectroscopy | Single molecule spectroscopy of rigid-rod ladder-type conjugated polymers reveals individual chromophore units on a polymer chain, exhibiting fluorescence linewidths of less than 1 nm. Whereas the fluorescence from a single chromophore is fully linearly polarized at low temperatures, a number of exc... | Single molecule spectroscopy; Intramolecular energy transfer; Chromophore spectroscopy; Chromophores; Rigid-rod; Ladder-type | 2004 |
3 |
![]() | Lupton, John Mark | Unraveling the inhomogeneously broadened absorption spectrum of conjugated polymers by single-molecule light-harvesting action spectroscopy | The distribution of chromophores in single polymer chains is revealed by photoluminescence excitation spectroscopy under excitation of the backbone and detection of emission from an end cap. Spectral broadening in excitation exceeds that in emission. An increase in vibronic coupling for shorter (h... | Spectral broadening; Chromophores | 2009-10 |