Creator | Title | Description | Subject | Date | ||
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1 |
![]() | Armentrout, Peter B. | Effect of kinetic and electronic energy on the reactions of Cr+ with H2, HD, and D2 | The reactions of atomic chromium ions with H2 , HD, and D2 are examined using guided ion beam tandem mass spectrometry. The ground electronic state (6S) is found to react inefficiently. The thresholds of these data are analyzed to yield a 0 K bond dissociation energy for CrH+ of 1.37 ± 0.09 eV (31... | Chromium ions; Hydrogen; Deuteride; Bond energy | 1987 |
2 |
![]() | Armentrout, Peter B. | Guided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energies | The kinetic energy dependence of the reactions of Crn+ (n=2-18) with O2 are studied in a guided ion beam mass spectrometer. A variety of CrmO2+, CrmO+, and Crm+ product ions, where m≤n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster ions. React... | Metal clusters; Chromium ions; Oxygen; Oxygen; Bond energies; Exothermic reactions | 1998 |
3 |
![]() | Armentrout, Peter B. | Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energies | The kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form... | Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions | 1998 |