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CreatorTitleDescriptionSubjectDate
1 Miller, Joel Steven; Epstein, Arthur J.Anomalous charge transport phenomena in the molecular-based magnet V(TCNE)x.y(solvent)We present charge transport studies on recently developed molecular-based magnets V(TCNE)x. y(solvent) (TCNE= tetracyanoethylene) which show local magnetic ordering at temperatures, T, as high as 400 K. V(TCNE), .y(solvent) prepared from the solvent CH2Cl2 has o(300 K) - 10-3 S/cm, and that prepar...Frequency; Conductivity; Spin1993
2 Miller, Joel Steven; Epstein, Arthur J.Anomalous magnetoresistance in high-temperature organic-based magnetic seminconducting V(TCNE)x filmsAnomalous positive magnetoresistance (MR) in high temperature organic-based magnet V(TCNE)x (TCNE=tetracynoethylene) thin films is reported. MR increases linearly with applied magnetic field and shows a maximum at the ferrimagnetic ordering temperature. The suggested roles of oppositely spin pola...Spin; Ferrimagnetic; Resistance2003
3 Miller, Joel Steven; Epstein, Arthur J.Complex ac susceptibility studies of the disordered molecular based magnets V(TCNE)x: role of spinless solventThe effect of different spinless solvents on the magnetism of V(TCNE)x . y(solvent) (TCNE= tetracyanoethylene) is studied by temperature (T) dependent ac susceptibility above 2.3 K. Though V(TCNE)x.y(CH2Cl2) has a critical temperature Tc -400 K, for V(TCNEx.y(C4H8O), Tc -205 K and the coercive field...Magnetization; Spin; Temperature1993
4 Miller, Joel Steven; Epstein, Arthur J.Ferrimagnetic resonance in films of vanadium [tetracyanoethanide]x, grown by chemical vapor depositionFerrimagnetic resonance (FMR) measurements in thin films of V[TCNE]x grown by chemical vapor deposition exhibit a series of sharp lines at 300 K. The orientational dependence of these lines is a result of the sample geometry provided the magnetization tracks the applied magnetic field. The FMR inten...Spin; Anisotropy; Magnetization2004
5 Mattis, Daniel C.Few-body problem on a latticeThe author explores some of the inherent simplifications of "quantum lattice physics." He distinguishes between fermions and bosons and analyzes the n-body problem for each, with n = 1,2,3... typically a small number. With delta-function (zero-range) interactions, the three-body problem on a lattice...Quantum; Electrons; Spin1986
6 Miller, Joel StevenInterpenetrating three-dimensional rutile-like frameworks. Crystal structure and magnetic properties of MnII[C(CN)3]2The interpenetrating double-density rutile-like structure and magnetic properties of MnII[C(CN)3]2 are determined.Spin; Bond; Coupling1998
7 Miller, Joel Steven; Epstein, Arthur J.Linear chain ferromagnetic charge transfer compoundsCharge transfer complexes possessing a ... DADA ... structure with both the donor, D, and acceptor, A, being S = 1/2 radicals may exhibit cooperative magnetic phenomena. The complex [Fe(C5Me5)2]+ [TCNQ]-. exhibits metamagnetic behavior. The similarly structured [TCNE]-. and [C4(CN)6]-. complexes ar...Spin; Exchange; Molecular1986
8 Miller, Joel Steven; Epstein, Arthur J.Magnetic properties and critical behavior of Fe(tetracyanoethylene) 2.x(CH2Cl2): a high-Tc molecule-based magnetWe report magnetic studies of Fe(TCNE)2•x(CH2Cl2), a member of the family of high-Tc molecule-based magnets, M(TCNE)x•y (solvent) (M=V, Mn, TCNE=tetracyanoethelyne). Based on extensive static and dynamic magnetic measurements we show that this system has a complex magnetic behavior, with a mixtu...Solvent; Anisotropy; Spin2000
9 Ailion, David CharlesMolecular reorientations in the ordered phases of KCN and NaCN studied by NMRWe have measured 13C and 23Na NMR spin-lattice relaxation times as a function of temperature in KCN and NaCN in order to study the head-to-tail reorientations of the CN- molecules in the two low-temperature ordered phases. We have combined our data with those of dielectric-response and ionic-thermal...Spin; Interactions; Fluctuations1984
10 Miller, Joel Steven; Epstein, Arthur J.Molecule-based magnets - an overviewMolecule-based* magnets are a broad, emerging class of magnetic materials that expand the materials properties typically associated with magnets to include low density, transparency, electrical insulation, and low-temperature fabrication, as well as combine magnetic ordering with other proper...Spin; Magnetization; Magnetic ordering2000
11 Mattis, Daniel C.New mapping for particles on lattices with hard-core interactionsA novel mapping between Hilbert spaces of unequal dimensionalities yields many-body states which exactly satisfy the no-double-occupancy constraints for particles on lattices in arbitrary spatial dimensions. After proving the states are complete, we apply them to Nagaoka's theorem and the t-J model...Ferromagnetism; Spin; Dimensions1996
12 Miller, Joel StevenNoncollinear antiferromagnetic structure of the molecule-based magnet Mn[N(CN)2]2The crystallographic and magnetic properties of the Mn[N(CN)2]2 compound have been investigated by dc magnetization, ac susceptibility, specific heat, and zero-field neutron diffraction on polycrystalline samples. The magnetic structure consists of two sublattices which are antiferromagnetically cou...Spin; Crystal; Magnetic2000
13 Miller, Joel StevenStructure and physical properties of hexacyanomanganate(IV), [MnIV(CN)6]2-Hydrolytically unstable d3 [MnI V(CN)6]2- as the [N(PPh3)2]+ salt is crystallographically, spectroscopically, and magnetically characterized.Absorption; Magnetic; Spin1997
14 Miller, Joel StevenStructure, optical and magnetic behaviour of meso-tetraphenyl-porphyrinatoiron(III) tetracyanoethenide, [FeIII(TPP)]+[TCNE].-*The direct redox reaction between tetracyanoethylene (TCNE) and meso-tetraphenylporphyrinatoiron(II), [FeII(TPP)], formed the electron transfer salt (ETS) [FeIII(TPP)][TCNE], which has been structurally, spectroscopically, and magnetically characterized. It has an extended one-dimensional linear ch...Magnets; Spin; Electron2001
15 Miller, Joel StevenZero field splitting, field-dependent magnetization of mixed-valent S = 3/2 Diruthenium(II,III) tetracarboxylatesThe 2 K field-dependent magnetization, M(H), of S = 3/2 [RunII/III2(OAc)4]+ was studied. [RuII/III 2(OAc)4]+ exhibits an unusually low magnetization with respect to that predicted by the classical Brillouin function. This reduced value is a consequence of the large anisotropy arising from the large ...Spin; Coupling; Expressions2004
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