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| Creator | Title | Description | Subject | Date | ||
|---|---|---|---|---|---|---|
| 1 |
 | Armentrout, Peter B. | Guided ion beam studies of the reactions of Vn+ (n = 2-13) with D2: cluster-deuteride bond energies as a chemical probe of cluster electronic structure | The kinetic energy dependencies of the reactions of Vn+ (n=2 - 13) with D2 are studied in a guided ion beam tandem mass spectrometer. Products observed are VnD1 for all clusters and VnD2 + for n=4 - 13. All reactions are observed to exhibit thresholds, except for formation of VnD2 + for n =4,5,7,9,1... | Metal clusters; Vanadium ions; Bond energies; Endothermic reactions; Collision-induced dissociation; Transition metal ions; Deuterides | 2002 |
| 2 |
 | Armentrout, Peter B. | Kinetic-energy dependence of competitive spin-allowed and spin-forbidden reactions: V++CS2 | The kinetic-energy dependence of the V++CS2 reaction is examined using guided ion-beam mass spectrometry. Several different ion sources are used to systematically vary the V+ electronic state distributions and elucidate the reactivities of both the ground and excited state V+ cation. | Carbon disulfide; Vanadium ions; Transition metal ions; Bond energies; Endothermic reactions; Exothermic reactions | 1999 |
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