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1 Armentrout, Peter B.C+(2P)+H2(D2,HD)→CH+(CD+)+H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15eV c.m.Total cross sections for the reactions of carbon (1 + ) ions with isotopic molecular hydrogen (H2, D2, and HD) to form methyliumylidene (CH+ and CD+) have been measured using guided ion beam techniques. Cross sections are reported as a function of the translational energy of the reactants from th...Methyliumylidene; Endothermic reactions; Isotope effect; Threshold energy1986
2 Armentrout, Peter B.Reaction of Cr+, Mn+, Fe+, Co+, and Ni+ with O2 and N2O. Examination of the translational energy dependence of the cross sections of endothermic reactionsReactions of Cr+, Mn+, Fe+, Co+, and Ni+ with 02 and N20 to yield metal oxide ions are examined using an ion beam apparatus. Reaction cross sections a as a function of ion translational energy E are reported. With one exception, Fe+ + N20, the cross sections exhibit an energy threshold E0.Metal oxides; Endothermic reactions; Translational energy; Bond energy; Threshold energy1982
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