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| Creator | Title | Description | Subject | Date | ||
|---|---|---|---|---|---|---|
| 1 |
 | Miller, Joel Steven | 1H NMR investigation of the magnetic spin configuration in the molecule-based ferrimagnet [MnTFPP][TCNE] | 1H NMR line-shape measurements have been performed in the linear chain molecule-based ferrimagnet [MnTFPP][TCNE].xPhMe (TFPP=tetrakis(4-fluorophenyl)porphinato; TCNE=tetracyanoethylene) as a function of temperature. Hyperfine shifts of opposite sign were observed indicating the presence of two oppo... | Magnetization; Magnets; Paramagnetic | 2002 |
| 2 |
 | Miller, Joel Steven; Epstein, Arthur J. | Anomalous relaxation in a quasi-one-dimensional fractal cluster glass | The low-temperature spin glass state of the quasi-1D organic-based magnet [MnTPP]+[TCNE]- .x(1,3-C6H4Cl2) has unusually long relaxation times due to frustration induced by dipole-dipole interactions between fractal spin clusters. This long relaxation is investigated with in-field relaxation measurem... | Sweep rate; Bifurcation; Magnetization | 2004 |
| 3 |
 | Scarpulla, Michael | Carrier concentration dependencies of magnetization & transport in Ga1-xMnxAs1-yTey | We have investigated the transport and magnetization characteristics of Ga1-xMnxAs intentionally compensated with shallow Te donors. Using ion implantation followed by pulsed-laser melting, we vary the Te compensation and drive the system through a metal-insulator transition (MIT). This MIT is assoc... | Gallium arsenide; Ferromagnetic semiconductors; Magnetization; Resistivity | 2005 |
| 4 |
 | Miller, Joel Steven; Epstein, Arthur J. | Complex ac susceptibility studies of the disordered molecular based magnets V(TCNE)x: role of spinless solvent | The effect of different spinless solvents on the magnetism of V(TCNE)x . y(solvent) (TCNE= tetracyanoethylene) is studied by temperature (T) dependent ac susceptibility above 2.3 K. Though V(TCNE)x.y(CH2Cl2) has a critical temperature Tc -400 K, for V(TCNEx.y(C4H8O), Tc -205 K and the coercive field... | Magnetization; Spin; Temperature | 1993 |
| 5 |
 | Golden, Kenneth M. | Critical behavior of transport in lattice and continuum percolation models | It has been observed that the critical exponents of transport in the continuum, such as in the Swiss cheese and random checkerboard models, can exhibit nonuniversal behavior, with values different than the lattice case. Nevertheless, it is shown here that the transport exponents for both lattice a... | Ising model; Magnetization; Scaling | 1997 |
| 6 |
 | Miller, Joel Steven; Epstein, Arthur J. | Dynamic spin fluctuations in the molecular ferromagnet (DMeFc)(TCNE) | The static and dynamic magnetic properties of the molecular ferromagnet decamethylferrocenium tetracyanoethenide (DMeFc)(TCNE) are studied via the muon-spin-relaxation technique. Spontaneous order is observed in the ferromagnetic ground state below 5 K, while the muon-spin-relaxation rate in the par... | Magnetic; Magnetization; Paramagnetic | 2001 |
| 7 |
 | Symko, Orest George | Effect of crystal field on the magnetization of dilute hcp alloys | Magnetization measurements on very dilute single-crystal alloys of Mg-Mn, Zn-Mn, and Zn-Cr in the temperature range of 2-0.008 K show that the ground state of these systems is determined by fine-structure splitting. For Mg-Mn the fine-structure constant D is +0.006 K with an effective spin of f whil... | HCP alloys; Crystal field; Magnetization; Mg-Mn; Zn-Mn; Zn-Cr | 1982-04 |
| 8 |
 | Miller, Joel Steven; Epstein, Arthur J. | Effect of disorder on the linear and nonlinear magnetic susceptibilities of two manganeseporphryin-based magnets | We analyze the effects of disorder on the magnetic properties of two manganeseporphyrins, [MnTPP][TCNE] •. x(o-DCB) and [MnTPP][TCNE] . • y(o-Xy) and (TPP=meso-tetraphenylporphyrinato, TCNE=tetracyanoethylene, o-Xy=o-xylene, o-DCB=o-dichlorobenzene, x<_3,y<_1). We present data for the in- ... | Magnetization; Ferrimagnetic; Spins | 1997 |
| 9 |
 | Miller, Joel Steven; Epstein, Arthur J. | Effect of solvent on the magnetic properties of the high-temperature V[TCNE]x molecule-based magnet | The different magnetic behaviors of the V[TCNE]x (TCNE=tetracyanoethylene) magnet prepared via the reaction of TCNE and V(CO)6 in CH2Cl2 and the solvent-free chemical vapor deposition (CVD) of TCNE and V(CO)6 onto a glass substrate were determined. It was shown that the presence of noncoordinating C... | Magnetization; Molecule | 2001 |
| 10 |
 | Miller, Joel Steven; Epstein, Arthur J. | Ferrimagnetic resonance in films of vanadium [tetracyanoethanide]x, grown by chemical vapor deposition | Ferrimagnetic resonance (FMR) measurements in thin films of V[TCNE]x grown by chemical vapor deposition exhibit a series of sharp lines at 300 K. The orientational dependence of these lines is a result of the sample geometry provided the magnetization tracks the applied magnetic field. The FMR inten... | Spin; Anisotropy; Magnetization | 2004 |
| 11 |
 | Miller, Joel Steven; Epstein, Arthur J. | Ferromagnetic behavior and magnetic excitations in a molecular-based alternating-spin chain: decamethylchromocenium tetracyanoethenide | We report the study of magnetic properties of a molecular-based alternating-spin chain: metallocenium electron-transfer salt decamethylchromocenium tetracyanoethanide, [CrCp(*2)] [TCNE]. We give a modified spin-wave theory for the Heisenberg alternating-spin chains. The low-field susceptibility and... | TCNE; Magnetization | 1994 |
| 12 |
 | Miller, Joel Steven; Epstein, Arthur J. | Ferromagnetic behavior of decamethylchromocenium tetracyanoethenide, [CrCp*2][TCNE] | Studies on the magnetic properties of decamethylchromocenium tetracyanoethanide, [CrCp*2][TCNE] are reported herein. Near-zero field (H= 150 mG) data indicates a ferromagnetic transition with T(c)=3.65 K. The temperature dependence below T(c) can be fit to a mean-field result M=M(o)(1 - T(o))(1/2)... | Magnetic; Magnetization; Transition | 1993 |
| 13 |
 | Miller, Joel Steven; Epstein, Arthur J. | Ferromagnetism in molecular decamethylferrocenium tetracyanoethylenide: (DMeFc TCNE) | The temperature and magnetic field dependence of the magnetization and susceptibility of single-crystal decamethylferrocenium tetracyanoethenide demonstrate that this material is the first molecular compound with a ferromagnetic ground state. A spontaneous magnetization is observed for T < 4.8 K. T... | Magnetization; Ferromagnetic | 1987 |
| 14 |
 | Miller, Joel Steven; Epstein, Arthur J. | Ferromagnetism in molecular materials: decamethylferrocenium tetracyanoethanide [DMeFc][TCNE] (invited) | Ferromagnetism has only recently been observed in molecular materials. We present here a summary of the ferromagnetic phenomena observed in the molecular charge transfer salt, decamethylferrocenium tetracyanoethanide (DMeFc) (TCNE), and related compounds. A spontaneous magnetization is observed i... | Magnetic; Magnetization | 1988 |
| 15 |
 | Mattis, Daniel C. | Ground-state symmetry in XY model of magnetism | Numerical studies by Betts and Oitmaa have led those authors to conjecture that in the XY model the ground-state magnetization Mz is zero. This is a model of spins on a lattice with interactions - J(SnxSmx+SnySmy), that can also describe a hard-sphere boson fluid. In the present note I prove the c... | Ground state; Magnetization; Bipartite lattice | 1979-06 |
| 16 |
 | Miller, Joel Steven; Epstein, Arthur J. | Lattice- and spin-dimensionality crossovers in a linear-chain-molecule-based ferrimagnet with weak spin anisotropy | [MnOEP][HCBD], a member of the metalloporphyrin family of donor-acceptor molecule-based magnets, consists of isolated ferrimagnetic chains of alternating S=2, [MnOEP], and s=1/2, [HCBD] units (OEP=octaethylporphyrinato and HCBD=hexacyanobutadiene). Analysis of the exchange pathways reveals an exchan... | Magnetic; Magnetization; Interchain | 1997 |
| 17 |
 | Miller, Joel Steven; Epstein, Arthur J. | Magnetic phase diagram of a molecule-based ferrimagnet: weak ferromagnetism and multiple dimensionality crossovers | A detailed study of the magnetic behavior of the molecule-based magnet, [MnOEP][HCBD], (OEP=mesooctaethylporphyrinato, HCBD=hexacyanobutadiene) from 1.7 to 20 K was performed. The earlier reported magnetic transition at 19.6 K, ascribed to a crossover from a one-dimensional Heisenberg-like ferrimag... | Transition; Temperature; Magnetization | 1997 |
| 18 |
 | Mattis, Daniel C. | Magnetization of Ising model in nonzero magnetic field | Knowing only the zero-field magnetization (e.g., Yang's result) of the Ising model in any number of dimensions, one can construct a lower bound on m(h), the magnetization in finite field. Knowledge of u, the internal energy per bond, enables a more efficient lower bound to be constructed. Both are ... | Magnetization; Griffiths inequality | 1969 |
| 19 |
 | Miller, Joel Steven | Manganese(II)octabutoxynaphthalocyanine and its ferrimagnetic electron-transfer salt with TCNE | The magnetic susceptibility (x) of 1,6,10,15,19,25,28,32- octa-n-butoxynaphthalocyaninatomanganese(III) tetracyanoethanide can be fit to a Curie-Weiss expression with O=54 K for T>150 K, and the xT(T) data are consistent with linear chains and can be fit to a Seiden expression for alternating S=2 a... | Magnetic; Ordering; Magnetization | 2000 |
| 20 |
 | Williams, Clayton C. | Measurement of in-plane magnetization by force microscopy | We present data which show that the magnetic force microscope is capable of detecting the component of the magnetic field parallel to the surface of a sample under study. Images of bits in a Co-alloy thin-film disk and of laser-written bits in a TbFe film were taken with a magnetized tip tilted at ... | Co-alloy disc; Magnetization | 1988 |
| 21 |
 | Miller, Joel Steven; Epstein, Arthur J. | Molecule-based magnets - an overview | Molecule-based* magnets are a broad, emerging class of magnetic materials that expand the materials properties typically associated with magnets to include low density, transparency, electrical insulation, and low-temperature fabrication, as well as combine magnetic ordering with other proper... | Spin; Magnetization; Magnetic ordering | 2000 |
| 22 |
 | Miller, Joel Steven; Epstein, Arthur J. | Organic and molecular ferromagnets | Unlike common ferromagnets such as iron, nickel, cobalt or even cobalt-samarium and Nb-Fe-B, it is extremely rare for a discrete molecule, especially an organic or polymeric material, to have cooperative magnetic interactions. Since the mid-1980s a few such materials have been prepared which demon... | Magnetic; Magnetization; Temperature | 1992 |
| 23 |
 | Miller, Joel Steven; Epstein, Arthur J. | Photoinduced magnetism, dynamics, and cluster glass behavior of a molecule-based magnet | The dynamic susceptibility study of photoinduced magnetism in a molecule-based magnet, (K1-2xCo1+x [Fe(CN)6]. yH2O (0.2<_x<_0.4,y-5), is reported. Upon excitation with visible light the material has substantial changes in linear and nonlinear ac susceptibility and dc magnetization. The results d... | Magnetization; Light; Magnetometer | 2000 |
| 24 |
 | Miller, Joel Steven; Epstein, Arthur J. | Spin dilution in a ferromagnetic chain | We have systematically introduced spinless defects in the quasi-one-dimensional ferromagnetic system decamethylferrocenium tetracyanoethanide, [FeCp(2*)] [TCNE]. The three-dimensional ordering temperature Tc decreases rapidly with the concentration of spinless sites. The rate of decrease of Tc with... | Magnetic; Magnetization; Spinless | 1992 |
| 25 |
 | Miller, Joel Steven; Epstein, Arthur J. | Spin frustration and metamagnetic behavior in a molecular-based quasi 1-D-ferrimagnetic chain: (MnTPP)(TCNE) | We report an experimental observation of spin frustration and metamagnetic behavior in a quasi-1D ferrimagnetic chain, (MnTPP) + (TCNE) -. Metastability, hysteresis effects, and irreversibility of thermal and magnetic histories are observed in magnetization measurements. The "memory" phenomenon is ... | Magnetic; Magnetization; Anisotropy | 1993 |