Creator | Title | Description | Subject | Date | ||
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1 |
![]() | Armentrout, Peter B. | C+(2P) + H2(D2,HD)→CH+(CD+) + H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15 eV c.m. | Total cross sections for the reactions of carbon (1 + ) ions with isotopic molecular hydrogen (H2, D2 , and HD) to form methyliumylidene (CH+ and C D + ) have been measured using guided ion beam techniques. Cross sections are reported as a function of the translational energy of the reactants fro... | Ion-molecule reactions; Isotope effects; Translational energy; Threshold behavior; Endothermic reactions | 1986 |
2 |
![]() | Armentrout, Peter B. | Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HD | The hydrogen atom transfer reactions of helium (1 +) and neon(1+) ions with isotopic molecular hydrogen (H2 , D2 , and HD) are investigated using guided ion beam techniques. These reactions are exothermic, but are known to be extremely slow at thermal energies. The cross sections for formation of... | Transfer reactions; Ion-molecule reactions; Exothermic reactions; Hydrogen; Helium ions; Neon ions; Threshold behavior; Isotope effects | 1987 |
3 |
![]() | Armentrout, Peter B. | Spin-orbit state-selected reactions of Kr+(2P3/2 and 2P1/2) with H2, D2, and HD from thermal energies to 20 eV c.m. | Spin-orbit state-selected reactions of K r + (2Pj), J = 3/2 and / = 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form KrH+ and Kr D+ are investigated using guided ion beam techniques. Reaction cross sections for each spin-orbit state are measured as a function of the relative trans... | Spin-orbit; Krypton ions; Hydrogen isotopes; Isotope effects; Potential energy surfaces; Ion-molecule reactions | 1986 |
4 |
![]() | Armentrout, Peter B. | Spin-orbit state-selected reactions of Xe+(2P3/2 and 2P1/2) with H2, D2, and HD | Spin-orbit state-selected reactions of X e + (2Pj ), j = 3/2 and 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form X e H + and XeD + are studied using guided ion beam mass spectrometry. Reaction cross sections are determined as a function of reactant kinetic energy from near thermal ... | Spin-orbit; Xenon ions; Hydrogen isotopes; Isotope effects; Ion-molecule reactions | 1989 |