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Creator | Title | Description | Subject | Date |
251 |
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Voth, Gregory Alan; Ayton, Gary S. | Role of protein interactions in defining HIV-1 viral capsid shape and stability: a coarse-grained analysis | Coarse-grained models of the HIV-1 CA dimer are constructed based on all-atom molecular dynamics simulations. Coarse-grained representations of the capsid shell, which is composed of approximately 1,500 copies of CA proteins, are constructed and their stability is examined. A key interaction between... | Virus capsid; HIV-1; Viral capsid shape; Coarse-graining; CA dimer | 2010-01 |
252 |
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Miller, Joel Steven | Room temperature molecular/organic-based magnet | The Du Pont / Ohio State University research team made materials in the laboratory, then tested them for magnetism. To do so, they initially moved a magnet along the outside of a sealed tube containing a small blob of experimental material and an inert gas such as argon or nitrogen. "We've done it... | Bis(benzene)vanadium; Vanadium; Tetracyanoethylene; TCNE; Polymeric magnets; Room temperature | 1991 |
253 |
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Morse, Michael David | Rotational analysis of the 30 1 band of the Ã6Σ+ ← X̃6Σ + system of CrCCH | The spectrum of chromium acetylide, CrCCH, has been investigated in the near-infrared region (10 500-14 500 cm−1) and an intense band system is observed. The 310 band of this system has been investigated at high resolution (0.025 cm−1) and this system is identified as the ˜A6 + ← ˜X6 + syste... | | 2014-01-01 |
254 |
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Morse, Michael David | Rotationally resolved spectra of jet-cooled RuSi | We report the first gas-phase spectroscopic investigation of diatomic ruthenium silicide (RuSi). The molecules were produced by laser ablation of a Ru disk into a flow of helium carrier gas containing 0.5% SiH4, and were cooled in a supersonic expansion. The RuSi molecules were then studied using re... | | 2007 |
255 |
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Morse, Michael David | Rotationally resolved spectra of jet-cooled VMo | The Author's report the first gas-phase spectroscopic investigation of diatomic vanadium molybdenum (VMo). The molecules were produced by laser ablation of a VMo alloy disk and cooled in a helium supersonic expansion. The jet-cooled VMo molecules were studied using resonant two-photon ionization sp... | | 2007 |
256 |
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Morse, Michael David | Rotationally resolved spectra of Pt? | High-resolution laser-induced fluorescence spectroscopy has been used to investigate the 18 163 cm21 band of Pt2 in a supersonically cooled molecular beam. Rotational constants of the ground and excited states were extracted from the rotationally resolved spectrum and determined to be B0'=0.031 754(... | | 2002 |
257 |
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Morse, Michael David | Rotationally resolved spectroscopy of jet-cooled NbMo | Rotationally resolved resonant two-photon ionization spectra of jet-cooled NbMo are reported for the first time. A vibronic spectrum of NbMo was recorded in the 17 300?22 300 cm?1 spectral region. Although the observed bands could not be grouped into electronic band systems, four excited vibronic le... | | 2007 |
258 |
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Morse, Michael David | Rydberg and pulsed field ionization-zero electron kinetic energy spectra of YO | A spectroscopic study of the Rydberg states of YO accessed from particular rotational levels of the A 2II1/2, v=0 state has been combined with a pulsed field ionization, zero electron kinetic energy (PFI-ZEKE) investigation. The results provide accurate values of the ionization energy of YO, ioniz... | | 1999 |
259 |
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Armentrout, Peter B.; Morse, Michael David | Rydberg and pulsed field ionization-zero electron kinetic energy spectra of YO | A spectroscopic study of the Rydberg states of YO accessed from particular rotational levels of the A²Π½, v=0 state has been combined with a pulsed field ionization, zero electron kinetic energy (PFI-ZEKE) investigation. The results provide accurate values of the ionization energy of YO, ionizati... | Ionization energy; Rydberg spectra; Yttrium monoxide | 1999 |
260 |
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Olson, Randall J.; Coldwell, Karin D.; Compton, Bruce J.; Giddings, John C. | Sedimentation field-flow fractionation: a method for studying particulates in cataractous lens | It is shown that the technique of sedimentation field-flow fractionation (sedimentation [sed] FFF) can be used to determine the particle content and particle size distribution of normal and cataractous lenses. A 31-year-old normal human lens, for example, showed a particle content of 1.5% by weight ... | Fractionation; Cataractous Lens; Particulates | 1984 |
261 |
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Stang, Peter J. | Self-assembly of coordinative supramolecular polygons with open binding sites | The design and synthesis of coordinative supramolecular polygons with open binding sites is described. Coordination-driven self-assembly of 2,6-bis(pyridin-4-ylethynyl)pyridine with 60? and 120? organoplatinum acceptors results in quantitative formation of a supramolecular rhomboid and hexagon, resp... | | 2010 |
262 |
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Stang, Peter J. | Self-selected formation of single discrete supramolecules with flexible, bidentate ligands in the coordination-driven self-assembly | Flexible donor ligands like 1,2-bis(3-pyridyl)ethyne or 1,4-bis(3-pyridyl)-1,3-butadiyne selfassemble into discrete 2-D supramolecules instead of infinite networks upon combination with organoplatinum 90, 120, and 180 degree acceptor units. These systems are unique examples of versatile pyridine... | Bidentate ligands; Flexible donor ligands; Supramolecules; Coordination-driven self-assembly | 2008 |
263 |
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Armentrout, Peter B. | Sequential bond energies and barrier heights for the water loss and charge separation dissociation pathways of Cd2+(H2O)n, n 3-11 | The bond dissociation energies for losing one water from Cd2+(H2O)n complexes, n=3?11, are measured using threshold collision-induced dissociation in a guided ion beam tandem mass spectrometer coupled with a thermal electrospray ionization source. Kinetic energy dependent cross sections are obtained... | | 2011 |
264 |
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Armentrout, Peter B. | The simplest b 2 + ion: determining its structure from its energetics by a direct comparison of the threshold collision-induced dissociation of protonated oxazolone and diketopiperazine | Energy-resolved collision-induced dissociation of b2 + ions derived from protonated GGG and GAG are compared with that of protonated diketopiperazine (H+DKP). Absolute dissociation cross sections are obtained using a guided ion beam tandem mass spectrometer and analyzed using statistical methods. T... | | 2012 |
265 |
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Armentrout, Peter B. | The simplest b2+ ion: determining its structure from its energetics by a direct comparison of the threshold collision-induced dissociation of protonated oxazolone and diketopiperazine | Energy-resolved collision-induced dissociation of b2 + ions derived from protonated GGG and GAG are compared with that of protonated diketopiperazine (H+DKP). Absolute dissociation cross sections are obtained using a guided ion beam tandem mass spectrometer and analyzed using statistical methods. Th... | | 2012-01-01 |
266 |
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Miller, Joel Steven; Epstein, Arthur J. | Solitons in nearly commensurate organic charge transfer crystals | X-ray diffuse scattering, magnetic, and conductivity studies of (N-methylphenazinium)x (phenazine)1-x (tetracyanoquinodimethan) [(NMPx(Phen)1-x (TCNQ)] show the formation of defect states for 0.50≤x≤0.54. These results are in agreement with the formation of solitons in a highly correlated quasi-... | Charge-transfer salts | 1983 |
267 |
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Miller, Joel Steven; Epstein, Arthur J. | Specific heat of decamethylferrocenium tetracyanoethanide (DMeFc)(TCNE) | We report the specific heat C(T) of (DMeFc)(TCNE) for temperatures 3 K < T < 50 K. We observe an anomaly at Tc-4.82 K corresponding to a transition to a three-dimensional (3D) macroscopic ferromagnet. A broad maximum at = 15 K corresponds to an exchange interaction of J = 35 K along the chain axis. ... | Temperature; Ferromagnetic; Magnetic | 1989 |
268 |
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Morse, Michael David | Spectroscopic analysis of jet-cooled AICu | Diatomic AlCu has been interrogated using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown to be X l?+, deriving from the 3&3dgd configuration, in agreement with theoretical predictions. The closed-shell nature of this molecule results in a l... | | 1993 |
269 |
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Morse, Michael David | Spectroscopic analysis of the open 3 d subshell transition metal aluminides: AIV, AICr, and AICo | Three open 3d subshell transition metal aluminides, AlV, AICr, and AlCo, have been investigated by resonant two-photon ionization spectroscopy to elucidate the chemical bonding in these diatomic molecules. The open nature of the 3d subshell results in a vast number of excited electronic states in th... | | 1994 |
270 |
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Morse, Michael David | Spectroscopic studies of jet-cooled AgAu and Au? | Resonant two-photon ionization spectroscopy has been applied to the jet-cooled Au? and AgAu molecules. Three new band systems of Au? and two new systems of the poorly characterized AgAu molecule have been observed. Excited state lifetime measurements have been made, and assignments of the excited s... | | 1991 |
271 |
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Morse, Michael David | Spectroscopic studies of jet-cooled AINi | Resonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the p... | | 1993 |
272 |
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Morse, Michael David | Spectroscopic studies of jet-cooled CuAg | Resonant two-photon ionization spectroscopy has been applied to jet-cooled diatomic CuAg. Four band systems have been observed, three of which have been rotationally resolved and analyzed. The ground state is X ??+ in symmetry, deriving from the 3d??cu4d??Ag?? molecular configuration. Its bond lengt... | | 1991 |
273 |
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Morse, Michael David | Spectroscopic studies of the jet-cooled aluminum trimer | Gas phase spectroscopic investigations of the jet-cooled aluminum trimer are reported using the technique of resonant two-photon ionization with mass spectrometric detection. A discrete band system in the 5200-6100 ? region is observed, consisting of an extended vibrational progression in a single ... | | 1987 |
274 |
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Morse, Michael David | Spectroscopy and electronic structure of jet-cooled Al? | Resonant two-photon ionization spectroscopy has been used to study the jet-cooled Al? molecule. The ground state has been conclusively demonstrated to be of 3IIu symmetry, deriving from the ???rr?u electronic configuration. High resolution studies have established the bond length of the X?IIu state ... | | 1990 |
275 |
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Morse, Michael David | Spectroscopy and electronic structure of jet-cooled GaAs | An optical spectrum, obtained by resonant two-photon ionization spectroscopy, is reported for jet-cooled diatomic gallium arsenide. The ground state is identified as X??-, deriving from a ??rr? molecular configuration, and is characterized by ?" = 215 cm-1, ?"exe" = 3 cm-1, and r0' = 2.53 ? 0.02 ?. ... | | 1989 |