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1 Miller, Joel StevenCharge transfer complexes of 2,4,6-tricyano-s-triazine with tetrathiafulvalene (TTF) and N,N,N' ,N'-tetramethyl-p-phenylenediamine (TMPD)Reaction of 2,4,6-tricyano-s-triazine (TCT) with tetrathiafulvalene (TTF) and N,N,N',N'-tetramethylp-phenylenediamine (TMPD) leads to 1 : 1 charge transfer complexes. The crystal structures of the TTF[TCT], as well as the decomposition product due to hydrolysis of the [TMPD][TCT], i.e. HTMPD]+[2,4-d...Electron; Solution; Hydrolysis2002
2 Miller, Joel Steven; Epstein, Arthur J.Spin frustration and metamagnetic behavior in a molecular-based quasi 1-D-ferrimagnetic chain: (MnTPP)(TCNE)We report an experimental observation of spin frustration and metamagnetic behavior in a quasi-1D ferrimagnetic chain, (MnTPP) + (TCNE) -. Metastability, hysteresis effects, and irreversibility of thermal and magnetic histories are observed in magnetization measurements. The "memory" phenomenon is ...Magnetic; Magnetization; Anisotropy1993
3 Stang, Peter J.Self-assembly of coordinative supramolecular polygons with open binding sitesThe design and synthesis of coordinative supramolecular polygons with open binding sites is described. Coordination-driven self-assembly of 2,6-bis(pyridin-4-ylethynyl)pyridine with 60? and 120? organoplatinum acceptors results in quantitative formation of a supramolecular rhomboid and hexagon, resp...2010
4 Armentrout, Peter B.Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HDThe hydrogen atom transfer reactions of helium (1 +) and neon(1+) ions with isotopic molecular hydrogen (H2 , D2 , and HD) are investigated using guided ion beam techniques. These reactions are exothermic, but are known to be extremely slow at thermal energies. The cross sections for formation of...Transfer reactions; Ion-molecule reactions; Exothermic reactions; Hydrogen; Helium ions; Neon ions; Threshold behavior; Isotope effects1987
5 Morse, Michael DavidResonant two-photon ionization spectroscopy of jet-cooled OsN: 520?418 nmThe optical transitions of supersonically cooled OsN have been investigated in the range from 19 200 to 23 900 cm?1 using resonant two-photon ionization spectroscopy. More than 20 vibronic bands were observed, 17 of which were rotationally resolved and analyzed. The ground state is confirmed to be 2...2011
6 Morse, Michael DavidSpectroscopic analysis of jet-cooled AICuDiatomic AlCu has been interrogated using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown to be X l?+, deriving from the 3&3dgd configuration, in agreement with theoretical predictions. The closed-shell nature of this molecule results in a l...1993
7 Morse, Michael DavidResonant two-photon ionization spectroscopy of jet-cooled tantalum carbide, TaCThe optical spectrum of diatomic TaC has been investigated for the first time, with transitions recorded in the range from 17 850 to 20 000 cm?1. Six bands were rotationally resolved and analyzed to obtain ground and excited state parameters, including band origins, upper and lower state rotational...2010
8 Miller, Joel Steven; Epstein, Arthur J.Microwave response of confined soliton pairs (Bipolarons) in (N-Methylphenazinium) x (Phenazine) 1-x (Tetracyanoquinodimethanide)The temperature-dependent dielectric response and conductivity at =1010 Hz is reported for the title compound, (NMP)x(Phen)i-x(TCNQ), in the regime 0.50<-x<-0.59, spanning commensurate, bipolaron, and incommensurate regimes. The large and strongly temperature-dependent dielectric constant and o-(101...Dielectric, Proposed, Electrons1987
9 Miller, Joel Steven; Epstein, Arthur J.Linear chain ferromagnetic charge transfer compoundsCharge transfer complexes possessing a ... DADA ... structure with both the donor, D, and acceptor, A, being S = 1/2 radicals may exhibit cooperative magnetic phenomena. The complex [Fe(C5Me5)2]+ [TCNQ]-. exhibits metamagnetic behavior. The similarly structured [TCNE]-. and [C4(CN)6]-. complexes ar...Spin; Exchange; Molecular1986
10 Morse, Michael DavidInfrared diode laser spectroscopy of jet-cooled NiCO, Ni(CO)?(??CO), and NI(CO)?(c??O)Gas phase infrared spectroscopic investigations of the CO vibration of jet-cooled NiCO, Ni(CO)3(13CO), and Ni(CO)3(C18O) are reported. The spectra were obtained using a recently assembled pulsed-discharge slit-jet IR diode laser spectrometer. The rotationally resolved spectrum of NiCO was collected ...2006
11 Miller, Joel StevenUsing fissionAtoms are just like people, both are lazy. Energy is a measure of work, i.e., more work implies more energy. Atoms do not like to work, hence they try to reduce the energy in their atomic system. For different elements the energy reduction occurs by reaction, e.g., an energetic sodium atom reacts w...Uranium-235; Uranium-2381966
12 Morse, Michael DavidResonant two-photon ionization spectroscopy of jet-cooled OsCThe optical spectrum of diatomic OsC has been investigated for the first time, with transitions recorded in the range from 17 390 to 22 990 cm?1. Six bands were rotationally resolved and analyzed to obtain ground and excited state rotational constants and bond lengths. Spectra for six OsC isotopomer...2008
13 Armentrout, Peter B.Guided ion beam and theoretical study of the reactions of Au+ with H2, D2, and HDReactions of the late third-row transition metal cation Au+ with H2, D2, and HD are examined using guided ion beam tandem mass spectrometry. A flow tube ion source produces Au+ in its 1S (5d10) electronic ground state level. Corresponding state-specific reaction cross sections for forming AuH+ an...2011
14 Miller, Joel StevenSynthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous mediaThe reaction of (NBu4)3[VIII(ox)3] (1, ox = oxalate) and M(II) (M= Fe, Co, Ni, Cu) ions in MeCN, leads to the isolation of V-based coordination polymers of [N(n-Bu)4][FeIIVIII(ox)3]? 0.30{[N(n-Bu)4](BF4)} (2), [N(n-Bu)4][CoIIVIII(ox)3]?0.75{[N(n-Bu)4](BF4)} (3), [N(n-Bu)4][NiIIVIII(ox)3]?0.20{[N(n...Magnetic; Coupling; Diffraction2006
15 Morse, Michael DavidResonant two-photon ionization spectroscopy of jet-cooled NiPtResonant two-photon ionization spectroscopy of jet-cooled NiPt has been used to investigate the possibility of <f-electron contributions to the bonding in this species. Based on an abrupt onset of predissociation, the bond strength of NiPt is assigned as D0 (NiPt) = 2.798 ? 0.003 eV. Comparisons of ...1989
16 Miller, Joel StevenPotential technology directions of molecular metalsIn the past decade, anisotropic molecular conductors have been found which possess unusual electrical, optical, magnetic, and in some cases mechanical properties. Exploiting these properties for specific devices is inevitable, and a number of diverse applications of molecular metals have been repor...Molecular metals1979
17 Armentrout, Peter B.Probes of spin conservation in heavy metal reactions: experimental and theoretical studies of the reactions of Re+ with H2, D2, and HDA guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cation, Re1, with molecular hydrogen and its isotopologues. A flow tube ion source produces Re1 in its 7S3 electronic ground state.Endothermic reactions; Transition metal ions; Rhenium ions; Dihydrogen2004
18 Armentrout, Peter B.Statistical modeling of competitive threshold collision-induced dissociationCollision-induced dissociation of (R1OH)Li+(R2OH) with xenon is studied using guided ion beam mass spectrometry. R1OH and R2OH include the following molecules: water, methanol, ethanol, 1-propanol, 2-propanol, and 1-butanol. In all cases, the primary products formed correspond to endothermic loss of...Collision-induced dissociation; Xenon ions; Alcohols1998
19 Miller, Joel Steven; Epstein, Arthur J.Effect of disorder on the linear and nonlinear magnetic susceptibilities of two manganeseporphryin-based magnetsWe analyze the effects of disorder on the magnetic properties of two manganeseporphyrins, [MnTPP][TCNE] •. x(o-DCB) and [MnTPP][TCNE] . • y(o-Xy) and (TPP=meso-tetraphenylporphyrinato, TCNE=tetracyanoethylene, o-Xy=o-xylene, o-DCB=o-dichlorobenzene, x<_3,y<_1). We present data for the in- ...Magnetization; Ferrimagnetic; Spins1997
20 Wight, Charles AlbertThermal analysis of high explosives: liquid state decomposition of RDXNonisothermal thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) have been applied to the thermal decomposition of RDX. Model-free isoconversional analysis of TGA and DSC traces show that RDX primarily evaporates in an open pan with an activation energy of Eα -100 kJ ...RDX; Plastic explosives; Decomposition; Thermogravimetric analysis; Differential scanning calorimetry2000
21 Armentrout, Peter B.Oxidation reactions at variably sized transition metal centers: Fen+ and Nbn+ + O2 (N=1-3)Cross sections for the reactions of Fen+ and Nbn+ (n = 1-3) with 02 are measured as a function of kinetic energy over a range of 0 to > 10 eV. In all systems, analysis yields insight into the kinetics and thermochemistry of the oxidation processes. Nbn+ reaction with 02 exothermically near the Lange...Metal clusters; Nobium ions; Iron ions; Exothermic reactions1989
22 Morse, Michael DavidOptical spectroscopy of tungsten carbide (WC)Resonant two-photon ionization spectroscopy has been used to study the diatomic transition-metal carbide, WC. A low-resolution scan revealed a five-member vibrational progression beginning with the 0-0 band at 17 585 cm-1. Analysis of this progression yielded a vibrational frequency of ?'e8(184W12C)...2002
23 Morse, Michael DavidRotationally resolved spectroscopy of jet-cooled NbMoRotationally resolved resonant two-photon ionization spectra of jet-cooled NbMo are reported for the first time. A vibronic spectrum of NbMo was recorded in the 17 300?22 300 cm?1 spectral region. Although the observed bands could not be grouped into electronic band systems, four excited vibronic le...2007
24 Morse, Michael DavidElectron spin resonance investigation of Sc?+ in neon matrices and assignment of its ground electronic state as X ???. comparison with theoretical calculationsThe discandium radical cation, Sc+2 , has been isolated in neon matrices at 4 K and studied by electron spin resonance (ESR) spectroscopy and theoretical methods. It was produced by the x-irradiation of neon matrix samples containing neutral ScZ which was formed by trapping the products generated fr...1993
25 Miller, Joel Steven; Epstein, Arthur J.Magnetization and dynamics of reentrant ferrimagnetic spin-glass [MnTPP]::+[TCNE].-.2PhMeWe present direct current (dc) magnetization M(T,H) and alternating current (ac) susceptibility Xac(T,H,f) data for the quasi-one-dimensional molecule-based ferrimagnet [MnTPP]::+[TCNE].-.•2PhMe (TPP=meso-tetraphenylporphyrinato, TCNE=tetracyanoethylene). Static scaling of the real part X' of ...Ferrimagnetic order; Magnetism1996
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