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CreatorTitleDescriptionSubjectDate
1 Minteer, Shelley D.Utilizing DNA for electrocatalysis: DNA-Nickel aggregates as anodic electrocatalysts for methanol, ethanol, glycerol, and glucoseDNA-nickel aggregates were electrodeposited onto glassy carbon electrode surfaces and have shown electrocatalytic activity for oxidation of methanol, ethanol, glycerol, and glucose at room temperature in alkaline solutions. Bulk electrolysis oxidation products identified by 13C NMR include carbonate...2013-01-01
2 Armentrout, Peter B.Collision-induced dissociation of Fen+ (n=2-10) with Xe: ionic and neutral iron binding energiesCross sections for collision-induced dissociation (CID) of Fen+ with Xe, 2≤n≤10, are presented. Experiments were performed on a newly constructed guided ion beam mass spectrometer, the design and capabilities of which are described in detail. The single mechanism for dissociation of iron cluster...1989
3 Miller, Joel StevenFerrimagnetic ordering of one-dimensional N,N'-dicyanoquinone diimine (DCNQI) electron transfer salts with porphyrinatomanganese(II)*The redox reaction between N,N'-dicyanoquinone diimines (DCNQIs) and porphyrinatomanganese(II) produced electron transfer salts (ETSs), [MnIIITMesP]+[DMeO-DCNQI]-. 1 (MnIIITMesP=meso-tetrakis(2,4,6- trimethylphenyl)porphyrinatomanganese(III), DMeO-DCNQI=2,5-dimethoxy-N,N'-dicyanoquinone diimine) an...Transitions; Interactions; Magnetic2001
4 Miller, Joel StevenFerrimagnetic ordering of a methylthio-substituted planar porphyrin based electron transfer salt, octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(III) tetracyanoethanideThe direct redox reaction between tetracyanoethylene (TCNE) and a planar porphyrinatomanganese(II), octakis(2,3,7,8,12,13,17,18-methylthio)porphyrinatomanganese(II), MnIIOMTP, produced a polymeric electron transfer salt (ETS), that has been structurally and magnetically characterized. The ETS belon...Magnetic; Temperature; Coupling2000
5 Morse, Michael DavidElectronic structure of the 4 d transition metal carbides: dispersed fluorsecence spectroscopy of MoC, RuC, and PdCDispersed fluorescence studies of the diatomic molecules MoC, RuC, and PdC are reported. New states identified in MoC and RuC are the [...]2??12??, ?,??? states and the [...]2??12??, ??? state, respectively. Five states are observed by dispersed fluorescence in PdC. The ground state is found to be [...2011
6 Morse, Michael DavidElectronic structure of the 4d transition metal carbides: dispersed fluorescence spectroscopy of MoC, RuC, and PdCDispersed fluorescence studies of the diatomic molecules MoC, RuC, and PdC are reported. New states identified in MoC and RuC are the [...]2?112?1, 3,1?2 states and the [...]2? 312?1, 1?2 state, respectively. Five states re observed by dispersed fluorescence in PdC. The ground state is found to be [...2001
7 Morse, Michael DavidPhotodissociation measurements of bond dissociation energies: Ti?+, V?+, Co?+, and Co?+The bond dissociation energies of Ti2+, V+2 , Co+2, and Co: have been measured from the sudden onset of predissociation in the photodissociation spectra of these molecules, yielding values of D?(Ti+2)=2.435+0.002 eV, D?(V+2)=3.140?0.002 eV, D?(Co+2)=2.7651?0.001 eV, and D?(Co+3)=2.086?0.002 eV. Thes...1993
8 Armentrout, Peter B.Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m.Cross sections for the reactions of Ar+ with H2, D2, and HD to form ArH + and ArD + are measured using a new guided ion beam tandem mass spectrometer which affords an experimental energy range from 0.05 to 500 eV laboratory. The apparatus and experimental techniques are described in detail. Cross se...Translational energy; Ion-molecule reactions; Ion energy; Argon; Hydrogen; Endothermic reactions1985
9 Morse, Michael DavidDispersed fluorsecence spectroscopy of AINi, NiAu, and PtCuDispersed fluorescence studies of AlNi, NiAu, and PtCu have been performed, providing spectroscopic information about the ground and low-lying excited electronic states. Vibrational frequencies are reported for the ground X 2?5/2 state of all three molecules. In the case of AlNi, fluorescence to all...2003
10 Morse, Michael DavidOptical spectroscopy of jet-cooled FeC between 12 000 and 18 100 cm-?Iron monocarbide has been investigated between 12 000 and 18 100 cm21 in a supersonic expansion by resonant two-photon ionization spectroscopy. Six new electronic states have been identified for which origins relative to the ground state have been determined. Three of these possess ?"=3, one possess...1997
11 Morse, Michael DavidOptical spectroscopy of tungsten carbide (WC)Resonant two-photon ionization spectroscopy has been used to study the diatomic transition-metal carbide, WC. A low-resolution scan revealed a five-member vibrational progression beginning with the 0-0 band at 17 585 cm-1. Analysis of this progression yielded a vibrational frequency of ?'e8(184W12C)...2002
12 Armentrout, Peter B.The bond energy of ReO+: Guided ion-beam and theoretical studies of the reaction of Re+ (7S) with O2The kinetic-energy dependence of the Re+ + O2 reaction is examined using guided ion-beam mass spectrometry. The cross section for ReO+ formation from ground state Re+ (7S) is unusual, exhibiting two endothermic features. The kinetic energy dependence for ReO+ formation is analyzed to determine D0(Re...2013-01-01
13 Armentrout, Peter B.Activation of methane by size-elected iron cluster cations, Fen+ (n=2-15): cluster-CHx (x=0-3) bond energies and reaction mechanismsThe kinetic energy dependences of the reactions of Fen + (n=2 - 15) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. All reactions exhibit thresholds and two main products, FenD+ and FenCD2+, are formed.Metal clusters; Iron ions; Bond energies; Dehydrogenation; Endothermic reactions; Transition metal ions2001
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