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CreatorTitleDescriptionSubjectDate
251 Stang, Peter J.Self-selected formation of single discrete supramolecules with flexible, bidentate ligands in the coordination-driven self-assemblyFlexible donor ligands like 1,2-bis(3-pyridyl)ethyne or 1,4-bis(3-pyridyl)-1,3-butadiyne selfassemble into discrete 2-D supramolecules instead of infinite networks upon combination with organoplatinum 90, 120, and 180 degree acceptor units. These systems are unique examples of versatile pyridine...Bidentate ligands; Flexible donor ligands; Supramolecules; Coordination-driven self-assembly2008
252 Armentrout, Peter B.Sequential bond energies and barrier heights for the water loss and charge separation dissociation pathways of Cd2+(H2O)n, n 3-11The bond dissociation energies for losing one water from Cd2+(H2O)n complexes, n=3?11, are measured using threshold collision-induced dissociation in a guided ion beam tandem mass spectrometer coupled with a thermal electrospray ionization source. Kinetic energy dependent cross sections are obtained...2011
253 Armentrout, Peter B.The simplest b 2 + ion: determining its structure from its energetics by a direct comparison of the threshold collision-induced dissociation of protonated oxazolone and diketopiperazineEnergy-resolved collision-induced dissociation of b2 + ions derived from protonated GGG and GAG are compared with that of protonated diketopiperazine (H+DKP). Absolute dissociation cross sections are obtained using a guided ion beam tandem mass spectrometer and analyzed using statistical methods. T...2012
254 Armentrout, Peter B.The simplest b2+ ion: determining its structure from its energetics by a direct comparison of the threshold collision-induced dissociation of protonated oxazolone and diketopiperazineEnergy-resolved collision-induced dissociation of b2 + ions derived from protonated GGG and GAG are compared with that of protonated diketopiperazine (H+DKP). Absolute dissociation cross sections are obtained using a guided ion beam tandem mass spectrometer and analyzed using statistical methods. Th...2012-01-01
255 Miller, Joel Steven; Epstein, Arthur J.Solitons in nearly commensurate organic charge transfer crystalsX-ray diffuse scattering, magnetic, and conductivity studies of (N-methylphenazinium)x (phenazine)1-x (tetracyanoquinodimethan) [(NMPx(Phen)1-x (TCNQ)] show the formation of defect states for 0.50≤x≤0.54. These results are in agreement with the formation of solitons in a highly correlated quasi-...Charge-transfer salts1983
256 Miller, Joel Steven; Epstein, Arthur J.Specific heat of decamethylferrocenium tetracyanoethanide (DMeFc)(TCNE)We report the specific heat C(T) of (DMeFc)(TCNE) for temperatures 3 K < T < 50 K. We observe an anomaly at Tc-4.82 K corresponding to a transition to a three-dimensional (3D) macroscopic ferromagnet. A broad maximum at = 15 K corresponds to an exchange interaction of J = 35 K along the chain axis. ...Temperature; Ferromagnetic; Magnetic1989
257 Morse, Michael DavidSpectroscopic analysis of jet-cooled AICuDiatomic AlCu has been interrogated using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown to be X l?+, deriving from the 3&3dgd configuration, in agreement with theoretical predictions. The closed-shell nature of this molecule results in a l...1993
258 Morse, Michael DavidSpectroscopic analysis of the open 3 d subshell transition metal aluminides: AIV, AICr, and AICoThree open 3d subshell transition metal aluminides, AlV, AICr, and AlCo, have been investigated by resonant two-photon ionization spectroscopy to elucidate the chemical bonding in these diatomic molecules. The open nature of the 3d subshell results in a vast number of excited electronic states in th...1994
259 Morse, Michael DavidSpectroscopic studies of jet-cooled AgAu and Au?Resonant two-photon ionization spectroscopy has been applied to the jet-cooled Au? and AgAu molecules. Three new band systems of Au? and two new systems of the poorly characterized AgAu molecule have been observed. Excited state lifetime measurements have been made, and assignments of the excited s...1991
260 Morse, Michael DavidSpectroscopic studies of jet-cooled AINiResonant two-photon ionization spectroscopy has been used to interrogate diatomic AlNi produced by laser vaporization of a 1:l alloy target in a supersonic molecular beam of helium. Although a large density of states in this molecule prohibits a concise elucidation of its electronic structure, the p...1993
261 Morse, Michael DavidSpectroscopic studies of jet-cooled CuAgResonant two-photon ionization spectroscopy has been applied to jet-cooled diatomic CuAg. Four band systems have been observed, three of which have been rotationally resolved and analyzed. The ground state is X ??+ in symmetry, deriving from the 3d??cu4d??Ag?? molecular configuration. Its bond lengt...1991
262 Morse, Michael DavidSpectroscopic studies of the jet-cooled aluminum trimerGas phase spectroscopic investigations of the jet-cooled aluminum trimer are reported using the technique of resonant two-photon ionization with mass spectrometric detection. A discrete band system in the 5200-6100 ? region is observed, consisting of an extended vibrational progression in a single ...1987
263 Morse, Michael DavidSpectroscopy and electronic structure of jet-cooled Al?Resonant two-photon ionization spectroscopy has been used to study the jet-cooled Al? molecule. The ground state has been conclusively demonstrated to be of 3IIu symmetry, deriving from the ???rr?u electronic configuration. High resolution studies have established the bond length of the X?IIu state ...1990
264 Morse, Michael DavidSpectroscopy and electronic structure of jet-cooled GaAsAn optical spectrum, obtained by resonant two-photon ionization spectroscopy, is reported for jet-cooled diatomic gallium arsenide. The ground state is identified as X??-, deriving from a ??rr? molecular configuration, and is characterized by ?" = 215 cm-1, ?"exe" = 3 cm-1, and r0' = 2.53 ? 0.02 ?. ...1989
265 Morse, Michael DavidSpectroscopy and electronic structure of jet-cooled NiCuDiatomic nickel-copper, NiCu, has been investigated by resonant two-photon ionization spectroscopy in a jet-cooled molecular beam. Six band systems have been identified over the range 11 500-16 500 cm-1. The ground state of NiCu has been determined to be X 2?5/2, with ?"e = 273.01 ? 1.15 cm-1, ?"exe...1988
266 Morse, Michael DavidSpectroscopy and electronic structure of jet-cooled NiPd and PdPtResonant two-photon ionization spectroscopy of jet-cooled NiPd and PdPt has revealed a dense vibronic spectrum for NiPd and a much more sparse spectrum for PdPt. Four vibrational progressions have been identified for NiPd, and three have been located for PdPt. High resolution investigations of NiPd...1990
267 Morse, Michael DavidSpectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limitSpectra of jet-cooled AlAr and AlKr have been collected over the range from 31 000 cm -? to the ionization limit, using the technique of resonant two-photon ionization spectroscopy with mass spectrometric detection. Adiabatic ionization potentials have been accurately measured for both molecules, an...1992
268 Morse, Michael DavidSpectroscopy of diatomic ZrF and ZrCl: 760 ? 555 nmThe optical spectrum of diatomic ZrF has been investigated, with transitions recorded in the range from 14 700 to 18 000 cm?1. Many bands have been observed, several of which can be grouped into three band systems. Rotationally resolved investigations are hampered by perturbations that are rampant ...2011
269 Morse, Michael DavidSpectroscopy of mixed early-late transition metal diatomics: ScNi, YPd, and ZrCoResonant two-photon ionization spectroscopy has been employed to investigate the spectra of the jet-cooled transition metal diatomics ScNi, YPd, and ZrCo, which are isovalent species which possess ~or are thought to possess! an X 2?+ ground state. Several electronic band systems have been observed f...1994
270 Morse, Michael DavidSpectrosopic studies of jet-cooled NiAu and PtCuSpectroscopic investigations of NiAu and PtCu have revealed that both molecules possess 2?5/2 ground electronic states, and are in this respect analogous to the isovalent molecule NiCu. The ground-state bond lengths (r?) have been measured as 2.351?0.001 ? and 2.335?0.001 ? for NiAu and PtCu, respe...1992
271 Morse, Michael DavidSpectrsocopy of Jet-cooled YCuOptical spectra of jet-cooled diatomic YCu have been recorded using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown experimentally to be of 1?+ symmetry, with a measured bond length of re"=2.6197(6) ? and a vibrational frequency of 193.21(24...1995
272 Miller, Joel StevenSpin crossover behavior of [FeII(isoxazole)6][BF4]2--a structural study[FeII(isoxazole)6][BF4]2 undergoes two reversible spin crossover transitions at 91 and 192 K and the single crystal structure determination reveals two different iron sites, Fe1 and Fe2, in a 1 : 2 ratio, with Fe1 attributed to the 91 K transition, and Fe2 attributed to the 192 K transition. This is...Transition; Magnetic; Temperature1999
273 Miller, Joel Steven; Epstein, Arthur J.Spin dilution in a ferromagnetic chainWe have systematically introduced spinless defects in the quasi-one-dimensional ferromagnetic system decamethylferrocenium tetracyanoethanide, [FeCp(2*)] [TCNE]. The three-dimensional ordering temperature Tc decreases rapidly with the concentration of spinless sites. The rate of decrease of Tc with...Magnetic; Magnetization; Spinless1992
274 Miller, Joel Steven; Epstein, Arthur J.Spin frustration and metamagnetic behavior in a molecular-based quasi 1-D-ferrimagnetic chain: (MnTPP)(TCNE)We report an experimental observation of spin frustration and metamagnetic behavior in a quasi-1D ferrimagnetic chain, (MnTPP) + (TCNE) -. Metastability, hysteresis effects, and irreversibility of thermal and magnetic histories are observed in magnetization measurements. The "memory" phenomenon is ...Magnetic; Magnetization; Anisotropy1993
275 Morse, Michael DavidSpin-forbidden c??+??X??+ band system of YFOptical spectra of jet-cooled diatomic YF have been recorded using resonant two-photon ionization spectroscopy. A vibrational progression corresponding to the c 3?1+?X 1?+ system has been identified. The vibrational frequency ?e' and anharmonicity ?'exe' of the c 3?+ state are 546.70 and 2.45 cm?1,...2007
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