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Creator | Title | Description | Subject | Date |
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Armentrout, Peter B. | Activation of methane by gold cations: guided ion beam and theoretical studies | The potential energy surface for activation of methane by the third-row transition metal cation, Au+, is studied experimentally by examining the kinetic energy dependence of this reaction using guided ion beam tandem mass spectrometry. A flow tube ion source produces Au+ primarily in its 1S0 (5d10) ... | | 2006 |
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Morse, Michael David | Infrared diode laser spectroscopy of jet-cooled NiCO, Ni(CO)?(??CO), and NI(CO)?(c??O) | Gas phase infrared spectroscopic investigations of the CO vibration of jet-cooled NiCO, Ni(CO)3(13CO), and Ni(CO)3(C18O) are reported. The spectra were obtained using a recently assembled pulsed-discharge slit-jet IR diode laser spectrometer. The rotationally resolved spectrum of NiCO was collected ... | | 2006 |
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Poulter, Charles Dale | Lethal mutations in the isoprenoid pathway of salmonella enterica | Essential isoprenoid compounds are synthesized using the 2-C-methyl-D-erythritol 4-phosphate (MEP) pathway in many gram-negative bacteria, some gram-positive bacteria, some apicomplexan parasites, and plant chloroplasts. The alternative mevalonate pathway is found in archaea and eukaryotes, includin... | Isoprenoids; Mutation; Bacteria; Antimicrobials | 2006 |
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Miller, Joel Steven | Magnetic behaviors of the metamagnetic and ferromagnetic phases of [Fe(C5Me5)2][TCNQ] (TCNQ = 7,7,8,8-tetracyano-p-quinodimethane). Determination of the phase diagram for the metamagnetic phase | The detailed magnetic behaviors of the ferro- (1FO) and metamagnetic (1MM) phases of [FeCp*2][TCNE] (Cp* = pentamethylcyclopentadienide; TCNE = tetracyanoethylene) aligned parallel to the applied magnetic field, H, were obtained using eicosane (E). The Tc for 1FO is 3.1 K from the maximum in the fr... | Properties; Temperature; Ordering | 2006 |
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Miller, Joel Steven | Magnetically ordered molecule-based assemblies | The development of molecules and assemblies of molecules exhibiting technologically important bulk properties, such as magnetic ordering, is an important worldwide research focus. Organic- and molecule-based magnets have been discovered and several families have been reported with magnetic orderin... | Organic-based; Lattices; Magnets | 2006 |
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Morse, Michael David | Resonant two-photon ionization spectroscopy of BNB | Triatomic BNB has been produced by laser ablation of a boron nitride rod in a supersonic expansion of helium carrier gas and has been investigated using resonant two-photon ionization spectroscopy in the visible region. The B? 2IIg?X? 2?u + band system has been recorded near 514 nm and is dominated ... | | 2006 |
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Miller, Joel Steven | Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media | The reaction of (NBu4)3[VIII(ox)3] (1, ox = oxalate) and M(II) (M= Fe, Co, Ni, Cu) ions in MeCN, leads to the isolation of V-based coordination polymers of [N(n-Bu)4][FeIIVIII(ox)3]? 0.30{[N(n-Bu)4](BF4)} (2), [N(n-Bu)4][CoIIVIII(ox)3]?0.75{[N(n-Bu)4](BF4)} (3), [N(n-Bu)4][NiIIVIII(ox)3]?0.20{[N(n... | Magnetic; Coupling; Diffraction | 2006 |
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Armentrout, Peter B. | Thermochemistry of the activation of N2 on iron cluster cations: guided ion beam studies of the reactions of Fen+ (n=1-19) with N2 | The kinetic energy dependences of the reactions of Fen + (n=1-19) with N2 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-15 eV. In addition to collision-induced dissociation forming Fem + ions, which dominate the product spectra, a variety of FemN2+ and FemN+ p... | Metal clusters; Iron ions; Dinitrogen; Endothermic reactions; Collision-induced dissociation; Bond energies | 2006 |