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Creator | Title | Description | Subject | Date |
1 |
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Miller, Joel Steven | Isolation and structural determination of {(1,1,2,2-tetracyano-1,2-ethanediyl)bis[imino(cyanomethylene)]}bis-(cyanamide) ion(2--), [C12N12]2--, a new cyanocarbon | The oxidative degradation of [N(PPh3)2]3[Mnilll(CN)6] leads to the isolation of the unprecedented [C12N12]2- dianion, which is characterized by single-crystal X-ray diffraction and spectroscopic techniques. | Cyanogen; Bond; Absorptions | 1995 |
2 |
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Miller, Joel Steven; Epstein, Arthur J. | Magnetic behavior of octaethylporphyrinatomanganese(III) tetracyanoethenide, [MnOEP][TCNE], and hexacyanobutadienide, [MnOEP][C4(CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling | [MnOEP][A] {A=[TCNE]'- and [C4(CN)6]'-} have been isolated as extended 1D coordination polymers with trans-U2"[A] bridging ligands with strong {A=[C4(CN)6].-} and weak {A=TCNE].-} ferromagnetic coupling as evidenced from the fit of the magnetic susceptibility to the Curie-Weiss law (0=5.1 and 67.1 K... | Crystals; Inversion; Coupling | 1995 |
3 |
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Morse, Michael David | Spectrsocopy of Jet-cooled YCu | Optical spectra of jet-cooled diatomic YCu have been recorded using resonant two-photon ionization spectroscopy in a supersonic expansion of helium. The ground state is shown experimentally to be of 1?+ symmetry, with a measured bond length of re"=2.6197(6) ? and a vibrational frequency of 193.21(24... | | 1995 |
4 |
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Morse, Michael David | Ultraviolet photoelectron spectroscopy of molybdenum and molybdenum monoxide anions | The 351 nm photoelectron spectra of Mo-and MoO- have been measured. The electron affinity of atomic molybdenum is 0.748(2) eV and that of molybdenum monoxide is 1.290(6) eV. The term energies of several MoO electronic states not previously observed are obtained and compared with ab initio prediction... | | 1995 |