UScholar Works
 
Filters: Date: "1986" Department: "Chemistry" Collection: "ir_uspace"
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CreatorTitleDescriptionSubjectDate
1 Armentrout, Peter B.C+(2P) + H2(D2,HD)→CH+(CD+) + H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15 eV c.m.Total cross sections for the reactions of carbon (1 + ) ions with isotopic molecular hydrogen (H2, D2 , and HD) to form methyliumylidene (CH+ and C D + ) have been measured using guided ion beam techniques. Cross sections are reported as a function of the translational energy of the reactants fro...Ion-molecule reactions; Isotope effects; Translational energy; Threshold behavior; Endothermic reactions1986
2 Armentrout, Peter B.C+(2P)+H2(D2,HD)→CH+(CD+)+H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15eV c.m.Total cross sections for the reactions of carbon (1 + ) ions with isotopic molecular hydrogen (H2, D2, and HD) to form methyliumylidene (CH+ and CD+) have been measured using guided ion beam techniques. Cross sections are reported as a function of the translational energy of the reactants from th...Methyliumylidene; Endothermic reactions; Isotope effect; Threshold energy1986
3 Armentrout, Peter B.Effect of kinetic and electronic energy on the reactions of Mn+ with H2, HD and D2Reactions of several electronic states of Mn+ with H2, HD, and D2 have been examined using guided ion beam mass spectroscopy. The excitation function for the ground state of Mn+ ( 75) has two regions: one of very low reactivity at threshold and another more efficient pathway at higher energies. In ...Ion-molecule reactions; Translational energy; Bond energy; Threshold behavior; Endothermic reactions; Metal ions; Manganese; Hydrogen1986
4 Miller, Joel Steven; Epstein, Arthur J.Ferromagnetic properties of one-dimensional decamethylferrocenium tetracyanoethylenide (1:1): [Fe(n5-C5Me5)2].+[TCNE].-[Fe(C5Me5)2].+ [TCNE].-- has been characterized by magnetic susceptibility to possess dominant ferromagnetic interactions; its structure has been determined by X-ray crystallography.Susceptibility; Crystal; Magnetic1986
5 Armentrout, Peter B.Kinetic energy dependence of Al+ + O2→AlO+ + OThe endothermic reaction of Al+ with O2 is studied using a guided ion-beam apparatus. The reaction cross section is measured as a function of kinetic energy from 0 to 20 eV. The threshold energy for the reaction, E0, is determined from an empirical model to be 3.64 ± 0.04 eV.Ion-molecule reactions; Translational energy; Threshold behavior; Endothermic reactions; Aluminum; Oxygen1986
6 Miller, Joel Steven; Epstein, Arthur J.Linear chain ferromagnetic charge transfer compoundsCharge transfer complexes possessing a ... DADA ... structure with both the donor, D, and acceptor, A, being S = 1/2 radicals may exhibit cooperative magnetic phenomena. The complex [Fe(C5Me5)2]+ [TCNQ]-. exhibits metamagnetic behavior. The similarly structured [TCNE]-. and [C4(CN)6]-. complexes ar...Spin; Exchange; Molecular1986
7 Armentrout, Peter B.Spin-orbit state-selected reactions of Kr+(2P3/2 and 2P1/2) with H2, D2, and HD from thermal energies to 20 eV c.m.Spin-orbit state-selected reactions of K r + (2Pj), J = 3/2 and / = 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form KrH+ and Kr D+ are investigated using guided ion beam techniques. Reaction cross sections for each spin-orbit state are measured as a function of the relative trans...Spin-orbit; Krypton ions; Hydrogen isotopes; Isotope effects; Potential energy surfaces; Ion-molecule reactions1986
8 Armentrout, Peter B.Transition metal cluster ion chemistryThe reactivity and thermochemistry of ionic metal atoms and clusters has been explored using guided ion beam mass spectrometry. With this apparatus, cross sections of ion-molecule reactions can be measured from thermal energies to hundreds of eV. Application to metal cluster chemistry demonstrates...Metal clusters; Manganese ions; Endothermic reactions1986
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