Creator | Title | Description | Subject | Date | ||
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1 | Miller, Joel Steven | Collinear ferromagnetism and spin orientation in the molecule-based magnets M[N(CN)2]2 (M=Co,Ni) | Zero-field unpolarized neutron powder diffraction has been used to study the low-T magnetic structure and T-dependent crystal structure of M[N(CN)2]2 (M=Co,Ni). Both compounds show collinear ferromagnetism with spin orientation along the c axis. The results provide the determination of a complete ma... | Magnetic; Diffraction; Structure | 1999 | |
2 | Miller, Joel Steven | Synthesis of layered (2-D) V-based bimetallic oxalates from non-aqueous media that cannot be synthesized from aqueous media | The reaction of (NBu4)3[VIII(ox)3] (1, ox = oxalate) and M(II) (M= Fe, Co, Ni, Cu) ions in MeCN, leads to the isolation of V-based coordination polymers of [N(n-Bu)4][FeIIVIII(ox)3]? 0.30{[N(n-Bu)4](BF4)} (2), [N(n-Bu)4][CoIIVIII(ox)3]?0.75{[N(n-Bu)4](BF4)} (3), [N(n-Bu)4][NiIIVIII(ox)3]?0.20{[N(n... | Magnetic; Coupling; Diffraction | 2006 |