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| Creator | Title | Description | Subject | Date | ||
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Miller, Joel Steven | [MeNC5H5]2[TCNE]2 (TCNE = tetracyanoethylene). Single crystal X-ray and neutron diffraction characterization of an exceptionally long 2.8 Å C-C bond | The reaction of N-methylpyridinium iodide, Mepy+I-, and tetracyanoethylene (TCNE) forms [Mepy]2[TCNE]2, which possesses [TCNE]2 2' with an intradimer C-C bond distance of 2.806(1)Å at 50 K from X-ray diffraction, and 2.801(4)Å at 50 K from neutron diffraction. In the IR it exhibits nChN absorption... | C-C bond; Tetracyanoethylene; Neutron diffraction; X-ray diffraction; Multicenter C-C bonding | 2009 |
| 2 |
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Miller, Joel Steven; Epstein, Arthur J. | Magnetic bistability and nucleation of magnetic bubbles in a layered 2D organic-based magnet [Fe(TCNE)(NCMe)2][FeC14] | The 2D layered organic-based magnet [Fe(TCNE)(NCMe)2][FeCl4] (TCNE ¼ tetracyanoethylene) exhibits a unique macroscopic magnetic bistability between the field-cooled and zero-field-cooled states, which cannot be explained by either superparamagnetic behavior or spin freezing due to spin glass orde... | Organic-based magnets; Tetracyanoethylene; Magnetic bistability; Nucleation | 2008-11 |
| 3 |
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Miller, Joel Steven | Room temperature molecular/organic-based magnet | The Du Pont / Ohio State University research team made materials in the laboratory, then tested them for magnetism. To do so, they initially moved a magnet along the outside of a sealed tube containing a small blob of experimental material and an inert gas such as argon or nitrogen. "We've done it... | Bis(benzene)vanadium; Vanadium; Tetracyanoethylene; TCNE; Polymeric magnets; Room temperature | 1991 |
| 4 |
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Miller, Joel Steven | Structure of CrIIF(NCMe)2BF4. Rietveld refinement of a component of a physical mixture of unknown composition | The reaction of CrII(NCMe)4(BF4)2 and [NBun 4][TCNE] (TCNE ¼ tetracyanoethylene) in CH2Cl2 forms a solid that is a mixture of an amorphous reduced-TCNE containing phase(s) and a crystalline component. Rietveld refinement of the high-resolution, synchrotron X-ray powder pattern enabled the determi... | Organic-based magnets; Powder X-ray diffraction; Tetracyanoethylene | 2008 |
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