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| Creator | Title | Description | Subject | Date | ||
|---|---|---|---|---|---|---|
| 1 |
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Armentrout, Peter B. | Collision-induced dissociation processes of Nb4+ and Fe4+: fission vs. evaporation | Despite the extensive effort devoted to research on gasphase metal clusters, quantitative thermodynamic data on such species are scarce. Such information is key to understanding and predicting the physical and chemical properties of clusters. Presently, bond energies are available primarily for tr... | Metal clusters; Nobium ions; Iron ions; Fission; Evaporation | 1988 |
| 2 |
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Miller, Joel Steven | Convenient synthesis of C5(CD3)5H. synthesis and characterisation of Fe{n5-C5(CD3)5}2 | The large scale synthesis of deuterio(pentamethylcyclopentadiene), C5(CD3)5H ([2H30]Cp*H), and subsequent synthesis of [2H30][Fe(n|-Cp*)2] is described, together with i.r., Raman, and solid state 2H n.m.r. spectroscopic characterisation. | Organometallic; Catalytic | 1988 |
| 3 |
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Armentrout, Peter B. | Energetics and dynamics in the reaction of Si+ with SiF4. Thermochemistry of SiFx and SiFx+ (x=1,2,3) | The title reaction is studied using guided ion beam mass spectrometry. Absolute reaction cross sections are measured as a function of kinetic energy from thermal to 40 eV, and three endothermic product channels are observed. The dominant SiF+ + SiF3 channel is only slightly endothermic, while the ... | Silicon fluoride; Ion-molecule reactions; Kinetic energy; Threshold behavior; Endothermic reactions | 1988 |
| 4 |
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Miller, Joel Steven; Epstein, Arthur J. | Ferromagnetism in molecular materials: decamethylferrocenium tetracyanoethanide [DMeFc][TCNE] (invited) | Ferromagnetism has only recently been observed in molecular materials. We present here a summary of the ferromagnetic phenomena observed in the molecular charge transfer salt, decamethylferrocenium tetracyanoethanide (DMeFc) (TCNE), and related compounds. A spontaneous magnetization is observed i... | Magnetic; Magnetization | 1988 |
| 5 |
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Miller, Joel Steven | Formation of a zwitterionic donor-acceptor compound based on N,N,N',N'-tetramethly-p-phenylenediamine and 7,7,8,8-tetracyanoperfluoro-p-quinodimethane | The reaction of the donor N,N,N',N'- tetramethyl-p-phenylenediamine (TMPD) with the acceptor 7,7,8,8-tetracyanoperfluoro-p-quinodimethane (TCNQF4) has led to the isolation of a novel type of zwitterionic donor-acceptor compound whose structure has been determined by X-ray crystallography. | Ccrystals; Single bond | 1988 |
| 6 |
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Miller, Joel Steven; Epstein, Arthur J. | New polymorph of 4,4'-(Butadiyne-1,4-diyl)-bis-(2,2,6,6-tetramethyl-4-hydroxypiperidin-1-oxyl) | A new polymorph of the title diradical has been characterized by X-ray diffraction, vibrational spectroscopy, and magnetic susceptibility; its radiation induced polymerization has not been achieved, but thermal treatment turns the crystals black and explosive decomposition occurs at-140 °C. | Ferromagnetic; Polymerization; Magnetic | 1988 |
| 7 |
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Miller, Joel Steven; Epstein, Arthur J. | Quest for a polymeric ferromagnet: a new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-1-oxy)butadiyne (invited) | A new polymorph of 1,4-bis(2,2,6,6-tetramethyl-4-oxy-4-piperidyl-l-oxy) butadiyne has been prepared and characterized by x-ray diffraction, infrared and Raman spectroscopies, and magnetic susceptibility. Unlike t h e Pccn-a phase, the B phase belongs to the Pca2y1 space group [a = 14.265(1) A(o),b ... | Molecular; Magnetic; Thermal | 1988 |
| 8 |
 |
Morse, Michael David | Resonant two-photon ionization spectroscopy of jet-cooled Pt? | The gas phase optical spectrum of jet-cooled Pt? has been investigated over the range of 11 300 to 26 300 cm -1 using resonant two-photon ionization spectroscopy in combination with time-of-flight mass spectrometry. Numerous vibronic bands are observed. Analysis of the data gives the location of som... | 1988 | |
| 9 |
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Morse, Michael David | Spectroscopy and electronic structure of jet-cooled NiCu | Diatomic nickel-copper, NiCu, has been investigated by resonant two-photon ionization spectroscopy in a jet-cooled molecular beam. Six band systems have been identified over the range 11 500-16 500 cm-1. The ground state of NiCu has been determined to be X 2?5/2, with ?"e = 273.01 ? 1.15 cm-1, ?"exe... | 1988 |
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