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Creator | Title | Description | Subject | Date |
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Morse, Michael David | A pair potentials study of matrix-isolated atomic zinc. II. Intersystem crossing in rare-gas clusters and matrices | The mechanism of 4p 1P1?4p 3PJ intersystem crossing (ISC) following excitation of the 4p 1P1 level of matrix-isolated atomic zinc is investigated using a pair potentials approach. This is achieved by extending earlier ISC calculations on the Zn?RG2 and Zn?RG3 complexes to the square planar Zn?RG4 ... | | 1998 |
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Morse, Michael David | First spectroscopic investigation of the 4 d transition metal monocarbide MoC | The first optical spectroscopic investigation of MoC has revealed a complicated vibronic spectrum consisting of about 35 bands between 17 700 and 24 000 cm-1. Analysis has shown the ground state to be the ?=0+ spin?orbit component of a 3?- state that derives from a 10?211?25rr42d 2 configuration. Th... | | 1998 |
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Armentrout, Peter B. | Guided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energies | The kinetic energy dependence of the reactions of Crn+ (n=2-18) with O2 are studied in a guided ion beam mass spectrometer. A variety of CrmO2+, CrmO+, and Crm+ product ions, where m≤n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster ions. React... | Metal clusters; Chromium ions; Oxygen; Oxygen; Bond energies; Exothermic reactions | 1998 |
4 |
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Armentrout, Peter B. | Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energies | The kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form... | Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions | 1998 |
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Miller, Joel Steven | Interpenetrating three-dimensional rutile-like frameworks. Crystal structure and magnetic properties of MnII[C(CN)3]2 | The interpenetrating double-density rutile-like structure and magnetic properties of MnII[C(CN)3]2 are determined. | Spin; Bond; Coupling | 1998 |
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Miller, Joel Steven | Isolation and structural determination of octacyanobutanediide, [C4(CN)8]2-; precursors to M(TCNE)x magnets(**) | The reaction of MI2.xMe3CN (M = Mn, Fe) and TCNE (tetracyanoethylene) leads to unprecedented [C4(CN)8]2-U4-metal complexes which have been crystallographically characterized and are precursors to M(TCNE)x-yS magnets. | Absorptions; Magnets; Bond | 1998 |
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Miller, Joel Steven; Epstein, Arthur J.; Zhang, Jie | Reentrance in the Mn(tetracyanoethylene)x.y(CH2Cl2) high-Tc molecule-based ferrimagnet | Results of static and dynamic magnetic studies of the compound Mn(TCNE)x•y(CH2Cl2) (TCNE =tetracyanoethylene) are reported. Curie-Weiss analysis of the high-temperature susceptibility data indicates a relatively strong exchange. The ac susceptibility, measured as a function of frequency and tempe... | Transition; Reentrant; Magnetic | 1998 |
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Morse, Michael David | Resonant two-photon ionization spectroscopy of jet-cooled RuC | A resonant two-photon ionization study of the jet-cooled RuC molecule has identified the ground state as a 1?+ state arising from the 10?211?25rr42?4 configuration. The 3?i state arising from the 10?211?25rr42?312?1 configuration lies very low in energy, with the 3?3 and 3?2 components lying only 76... | | 1998 |
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Armentrout, Peter B. | Statistical modeling of competitive threshold collision-induced dissociation | Collision-induced dissociation of (R1OH)Li+(R2OH) with xenon is studied using guided ion beam mass spectrometry. R1OH and R2OH include the following molecules: water, methanol, ethanol, 1-propanol, 2-propanol, and 1-butanol. In all cases, the primary products formed correspond to endothermic loss of... | Collision-induced dissociation; Xenon ions; Alcohols | 1998 |
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Miller, Joel Steven | Structure and magnetic properties of MnII[N(CN)2]2(pyrazine). An antiferromagnet with an interpenetrating 3-D network structure | Mn[N(CN)2]2(pyz) (pyz = pyrazine) orders antiferromagnetically at low temperature and possesses intralayer u-NCNCN and interlayer u-pyz ligands that form a pseudo-ReO3 interpenetrating network structure. | Dicyanamide; Polydentate; Temperature | 1998 |
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Miller, Joel Steven; Epstein, Arthur J. | Tetracyanoethylene-based organic magnets | Several classes of organic magnets based upon the tetracyanoethenide radical anion, [TCNE](.-), either unbound, (u), and (u4) bonded to zero, two and four metal sites have been reported. The putative (u4) bonded V(TCNE)x room temperature magnet has been extended to include M(TCNE)x(M = Mn, Fe, Co,... | Magnetization; Magnetic ordering; Oxidation | 1998 |
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Morse, Michael David | Two-photon ionization spectroscopy and all-electron ab initio study of LiCa | Resonant two-photon ionization spectra of LiCa have been obtained from a laser vaporization, supersonic expansion source. The ground state of the molecule is confirmed to be X 2?+. Three band systems have been observed near 15 282, 19 310, and 22 250 cm-1 and the upper states have been assigned as 2... | | 1998 |