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CreatorTitleDescriptionSubjectDate
1 Mattis, Daniel C.Bond asymmetry and high-Tc superconductivityWe propose a simple mechanism, anchored in weak-coupling BCS theory, which ties together the following facts: high Tc; quasi two dimensionality; orthorhombic distortion and/or disordered lines of oxygen; proximity to a metal-insulator transition; and anomalously small isotope effects.Distortion; Singularity; Oxygen1987
2 Armentrout, Peter B.Guided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energiesThe kinetic energy dependence of the reactions of Crn+ (n=2-18) with O2 are studied in a guided ion beam mass spectrometer. A variety of CrmO2+, CrmO+, and Crm+ product ions, where m≤n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster ions. React...Metal clusters; Chromium ions; Oxygen; Oxygen; Bond energies; Exothermic reactions1998
3 Armentrout, Peter B.Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energiesThe kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form...Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions1998
4 Armentrout, Peter B.Kinetic energy dependence of Al+ + O2→AlO+ + OThe endothermic reaction of Al+ with O2 is studied using a guided ion-beam apparatus. The reaction cross section is measured as a function of kinetic energy from 0 to 20 eV. The threshold energy for the reaction, E0, is determined from an empirical model to be 3.64 ± 0.04 eV.Ion-molecule reactions; Translational energy; Threshold behavior; Endothermic reactions; Aluminum; Oxygen1986
5 Armentrout, Peter B.Translational energy dependence of O+(4S) + N2 → NO+ + N from thermal energies to 30 eV c.m.Guided ion beam mass spectrometry is used to examine the kinetic energy dependence of the reaction of ground state atomic oxygen ion with molecular nitrogen. An 0 + (4S) source which produces less than 0.06% excited states is described. Cross sections for the NO+ + N product channel decrease with...Ion-molecule reactions; Translational energy; Threshold behavior; Endothermic reactions; Nitrogen; Oxygen1987
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