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Creator | Title | Description | Subject | Date |
1 |
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Miller, Joel Steven; Epstein, Arthur J. | Anomalous charge transport phenomena in the molecular-based magnet V(TCNE)x.y(solvent) | We present charge transport studies on recently developed molecular-based magnets V(TCNE)x. y(solvent) (TCNE= tetracyanoethylene) which show local magnetic ordering at temperatures, T, as high as 400 K. V(TCNE), .y(solvent) prepared from the solvent CH2Cl2 has o(300 K) - 10-3 S/cm, and that prepar... | Frequency; Conductivity; Spin | 1993 |
2 |
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Miller, Joel Steven; Epstein, Arthur J. | Anomalous magnetoresistance in high-temperature organic-based magnetic seminconducting V(TCNE)x films | Anomalous positive magnetoresistance (MR) in high temperature organic-based magnet V(TCNE)x (TCNE=tetracynoethylene) thin films is reported. MR increases linearly with applied magnetic field and shows a maximum at the ferrimagnetic ordering temperature. The suggested roles of oppositely spin pola... | Spin; Ferrimagnetic; Resistance | 2003 |
3 |
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Miller, Joel Steven; Epstein, Arthur J. | Complex ac susceptibility studies of the disordered molecular based magnets V(TCNE)x: role of spinless solvent | The effect of different spinless solvents on the magnetism of V(TCNE)x . y(solvent) (TCNE= tetracyanoethylene) is studied by temperature (T) dependent ac susceptibility above 2.3 K. Though V(TCNE)x.y(CH2Cl2) has a critical temperature Tc -400 K, for V(TCNEx.y(C4H8O), Tc -205 K and the coercive field... | Magnetization; Spin; Temperature | 1993 |
4 |
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Miller, Joel Steven; Epstein, Arthur J. | Ferrimagnetic resonance in films of vanadium [tetracyanoethanide]x, grown by chemical vapor deposition | Ferrimagnetic resonance (FMR) measurements in thin films of V[TCNE]x grown by chemical vapor deposition exhibit a series of sharp lines at 300 K. The orientational dependence of these lines is a result of the sample geometry provided the magnetization tracks the applied magnetic field. The FMR inten... | Spin; Anisotropy; Magnetization | 2004 |
5 |
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Mattis, Daniel C. | Few-body problem on a lattice | The author explores some of the inherent simplifications of "quantum lattice physics." He distinguishes between fermions and bosons and analyzes the n-body problem for each, with n = 1,2,3... typically a small number. With delta-function (zero-range) interactions, the three-body problem on a lattice... | Quantum; Electrons; Spin | 1986 |
6 |
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Miller, Joel Steven | Interpenetrating three-dimensional rutile-like frameworks. Crystal structure and magnetic properties of MnII[C(CN)3]2 | The interpenetrating double-density rutile-like structure and magnetic properties of MnII[C(CN)3]2 are determined. | Spin; Bond; Coupling | 1998 |
7 |
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Miller, Joel Steven; Epstein, Arthur J. | Linear chain ferromagnetic charge transfer compounds | Charge transfer complexes possessing a ... DADA ... structure with both the donor, D, and acceptor, A, being S = 1/2 radicals may exhibit cooperative magnetic phenomena. The complex [Fe(C5Me5)2]+ [TCNQ]-. exhibits metamagnetic behavior. The similarly structured [TCNE]-. and [C4(CN)6]-. complexes ar... | Spin; Exchange; Molecular | 1986 |
8 |
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Miller, Joel Steven; Epstein, Arthur J. | Magnetic properties and critical behavior of Fe(tetracyanoethylene) 2.x(CH2Cl2): a high-Tc molecule-based magnet | We report magnetic studies of Fe(TCNE)2•x(CH2Cl2), a member of the family of high-Tc molecule-based magnets, M(TCNE)x•y (solvent) (M=V, Mn, TCNE=tetracyanoethelyne). Based on extensive static and dynamic magnetic measurements we show that this system has a complex magnetic behavior, with a mixtu... | Solvent; Anisotropy; Spin | 2000 |
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Ailion, David Charles | Molecular reorientations in the ordered phases of KCN and NaCN studied by NMR | We have measured 13C and 23Na NMR spin-lattice relaxation times as a function of temperature in KCN and NaCN in order to study the head-to-tail reorientations of the CN- molecules in the two low-temperature ordered phases. We have combined our data with those of dielectric-response and ionic-thermal... | Spin; Interactions; Fluctuations | 1984 |
10 |
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Miller, Joel Steven; Epstein, Arthur J. | Molecule-based magnets - an overview | Molecule-based* magnets are a broad, emerging class of magnetic materials that expand the materials properties typically associated with magnets to include low density, transparency, electrical insulation, and low-temperature fabrication, as well as combine magnetic ordering with other proper... | Spin; Magnetization; Magnetic ordering | 2000 |
11 |
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Mattis, Daniel C. | New mapping for particles on lattices with hard-core interactions | A novel mapping between Hilbert spaces of unequal dimensionalities yields many-body states which exactly satisfy the no-double-occupancy constraints for particles on lattices in arbitrary spatial dimensions. After proving the states are complete, we apply them to Nagaoka's theorem and the t-J model... | Ferromagnetism; Spin; Dimensions | 1996 |
12 |
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Miller, Joel Steven | Noncollinear antiferromagnetic structure of the molecule-based magnet Mn[N(CN)2]2 | The crystallographic and magnetic properties of the Mn[N(CN)2]2 compound have been investigated by dc magnetization, ac susceptibility, specific heat, and zero-field neutron diffraction on polycrystalline samples. The magnetic structure consists of two sublattices which are antiferromagnetically cou... | Spin; Crystal; Magnetic | 2000 |
13 |
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Miller, Joel Steven | Structure and physical properties of hexacyanomanganate(IV), [MnIV(CN)6]2- | Hydrolytically unstable d3 [MnI V(CN)6]2- as the [N(PPh3)2]+ salt is crystallographically, spectroscopically, and magnetically characterized. | Absorption; Magnetic; Spin | 1997 |
14 |
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Miller, Joel Steven | Structure, optical and magnetic behaviour of meso-tetraphenyl-porphyrinatoiron(III) tetracyanoethenide, [FeIII(TPP)]+[TCNE].-* | The direct redox reaction between tetracyanoethylene (TCNE) and meso-tetraphenylporphyrinatoiron(II), [FeII(TPP)], formed the electron transfer salt (ETS) [FeIII(TPP)][TCNE], which has been structurally, spectroscopically, and magnetically characterized. It has an extended one-dimensional linear ch... | Magnets; Spin; Electron | 2001 |
15 |
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Miller, Joel Steven | Zero field splitting, field-dependent magnetization of mixed-valent S = 3/2 Diruthenium(II,III) tetracarboxylates | The 2 K field-dependent magnetization, M(H), of S = 3/2 [RunII/III2(OAc)4]+ was studied. [RuII/III 2(OAc)4]+ exhibits an unusually low magnetization with respect to that predicted by the classical Brillouin function. This reduced value is a consequence of the large anisotropy arising from the large ... | Spin; Coupling; Expressions | 2004 |