UScholar Works
 
Filters: Collection: "ir_uspace" Subject: "Bond energies" Type: "Text"
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1 Armentrout, Peter B.Activation of methane by size-elected iron cluster cations, Fen+ (n=2-15): cluster-CHx (x=0-3) bond energies and reaction mechanismsThe kinetic energy dependences of the reactions of Fen + (n=2 - 15) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. All reactions exhibit thresholds and two main products, FenD+ and FenCD2+, are formed.Metal clusters; Iron ions; Bond energies; Dehydrogenation; Endothermic reactions; Transition metal ions2001
2 Mattis, Daniel C.Bound exciton and hole: an exactly solvable three-body model in any number of dimensionsA three-body problem, concerning two holes in a nondegenerate valence band and a single electron in a conduction band, with strong short-range interactions, is solved exactly in any number of dimensions. The binding depends nontrivially on the ratio of the valence to conduction bandwidths (i.e., on ...Three-body problem; Trion; Bond energies1982-09
3 Mattis, Daniel C.Effect of spin variables and exciton motion on ground-state properties of the "trionWe solve a quantum three-body problem involving two holes and a single electron ("trion") in a two-band Hubbard model. The particles' spin and the exciton hopping matrix element are all included. We compare the results with those of a previous paper, in which these additional complications were abs...Three-body problem; Trion; Bond energies1983-03
4 Armentrout, Peter B.Guided ion beam studies of the reaction of Nin+ (n=2-16) with D2: nickel cluster-deuteride bond energiesThe kinetic-energy dependences of the reactions of Nin+ (n=2-16) with D2 are studied in a guided ion beam tandem mass spectrometer. The products observed are NinD+ for all clusters and NinD2 + for n=5-16. Reactions for formation of NinD+ are observed to exhibit thresholds, whereas cross sections for...Metal clusters; Nickel ions; Bond energies; Deuterides; Collision-induced dissociation; Endothermic reactions2002
5 Armentrout, Peter B.Guided ion beam studies of the reactions of Crn + (n=2-18) with O2: chromium cluster oxide and dioxide bond energiesThe kinetic energy dependence of the reactions of Crn+ (n=2-18) with O2 are studied in a guided ion beam mass spectrometer. A variety of CrmO2+, CrmO+, and Crm+ product ions, where m≤n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster ions. React...Metal clusters; Chromium ions; Oxygen; Oxygen; Bond energies; Exothermic reactions1998
6 Armentrout, Peter B.Guided ion beam studies of the reactions of Crn+ (n=1-18) with CO2: chromium cluster oxide bond energiesThe kinetic energy dependence of the reactions of Crn+ (n=1-18) with CO2 are studied in a guided ion beam mass spectrometer. The primary product ions are CrnO+, which then decompose by sequential loss of chromium atoms as the kinetic energy is increased. Simple collision-induced dissociation to form...Metal clusters; Chromium ions; Oxygen; Bond energies; Exothermic reactions; Endothermic reactions1998
7 Armentrout, Peter B.Guided ion beam studies of the reactions of Nin+ (n=2-18) with O2: nickel cluster oxide and dioxide bond energiesThe kinetic energy dependences of the reactions of Nin + (n=2 - 18) with O2 are studied in a guided ion beam tandem mass spectrometer. A variety of NimO2+, NimO+, and Nim+ product ions, where m<n, are observed, with the dioxide cluster ions dominating the products for all larger reactant cluster io...Metal clusters; Nickel oxide; Nickel dioxide; Bond energies; Collision-induced dissociation; Exothermic reactions2003
8 Armentrout, Peter B.Guided ion beam studies of the reactions of Vn+ (n = 2-13) with D2: cluster-deuteride bond energies as a chemical probe of cluster electronic structureThe kinetic energy dependencies of the reactions of Vn+ (n=2 - 13) with D2 are studied in a guided ion beam tandem mass spectrometer. Products observed are VnD1 for all clusters and VnD2 + for n=4 - 13. All reactions are observed to exhibit thresholds, except for formation of VnD2 + for n =4,5,7,9,1...Metal clusters; Vanadium ions; Bond energies; Endothermic reactions; Collision-induced dissociation; Transition metal ions; Deuterides2002
9 Armentrout, Peter B.Guided ion beam study of collision-induced dissociation dynamics: integral and differential cross sectionsThe low energy collision-induced dissociation (CID) of Cr(CO)6+ with Xe is investigated using a recently modified guided ion beam tandem mass spectrometer, in the energy range from 0 to 5 eV in the center-of-mass (CM) frame. The additions to the instrument, updated with a double octopole system, and...Collision-induced dissociation; Bond energies; Chromium carbonyl; Xenon2001
10 Armentrout, Peter B.Guided ion-beam studies of the kinetic-energy-dependent reactions of Con+ (n=2-16) with D2: cobalt cluster-deuteride bond energiesThe kinetic-energy-dependent cross sections for the reactions of Con + (n=2-16) with D2 are measured as a function of kinetic energy over a range of 0-8 eV in a guided ion-beam tandem mass spectrometer. The observed products are ConD+ for all clusters and ConD2+ for n=4,5,9-16.Cobalt ions; Metal clusters; Deuteride; Collision-induced dissociation; Endothermic reactions; Bond energies2005
11 Armentrout, Peter B.Guided ion-beam studies of the reactions of Con + (n=2-20) with O2: cobalt cluster-oxide and -dioxide bond energiesThe kinetic-energy dependence for the reactions of Con + (n=2-20) with O2 is measured as a function of kinetic energy over a range of 0 to 10 eV in a guided ion-beam tandem mass spectrometer. A variety of Com+ , ComO+, and ComO2 + (m<n) product ions is observed, with the dioxide cluster ions domina...Metal clusters; Cobalt ions; Collision-induced dissociation; Bond energies; Exothermic reactions; Endothermic reactions2005
12 Armentrout, Peter B.Kinetic energy dependence of association reactions. A new thermokinetic method for large systemsThe reactions of bare alkali metal ions (M+5Li+, Na+, or K+) with dimethoxyethane (CH3OCH2CH2OCH3 , (DXE) are studied using guided ion beam tandem mass spectrometry. The bimolecular reaction forms an associative M1(DXE) complex that is long-lived and dissociates back to the reactants. The kinetic en...Collision-induced dissociation; Association reactions; Bond energies; Dimethoxyethane; Alkali metal ions2003
13 Armentrout, Peter B.Kinetic-energy dependence of competitive spin-allowed and spin-forbidden reactions: V++CS2The kinetic-energy dependence of the V++CS2 reaction is examined using guided ion-beam mass spectrometry. Several different ion sources are used to systematically vary the V+ electronic state distributions and elucidate the reactivities of both the ground and excited state V+ cation.Carbon disulfide; Vanadium ions; Transition metal ions; Bond energies; Endothermic reactions; Exothermic reactions1999
14 Armentrout, Peter B.Methane activation by cobalt cluster cations, Con+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexesThe kinetic energy dependences of the reactions of Con + (n=2-16) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. The main products are hydride formation, ConD+, dehydrogenation to form ConCD2 +, and double dehydrogenation yielding ConC+.Cobalt ions; Transition metal ions; Bond energies; Endothermic reactions; Dehydrogenation; Deuterated methane2009
15 Armentrout, Peter B.Methane activation by nickel cluster cations, Nin+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexesThe kinetic energy dependences of the reactions of Nin+ (n=2-16) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. The main products are hydride formation NinD1, dehydrogenation to form NinCD2 1 , and double dehydrogenation yielding NinC1.Nickel ions; Metal clusters; Deuterated methane; Collision-induced dissociation; Endothermic reactions; Bond energies; Dehydrogenation2004
16 Wu, Yong-ShiNumerical study of the three-dimensional random-field Ising model at zero and positive temperatureIn this paper the three-dimensional random-field Ising model is studied at both zero temperature and positive temperature. Critical exponents are extracted at zero temperature by finite size scaling analysis of large discontinuities in the bond energy. The heat capacity exponent α is found to be n...Bond energies; Ground states2006-08
17 Armentrout, Peter B.Reactions of Pt+ with H2, D2, and HD: effect of lanthanide contraction on reactivity and thermochemistryA guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cation, Pt1, with molecular hydrogen and its isotopologs. A flow tube ion source produces Pt1 ions in its electronic ground state term and primarily in the lowes...Metal clusters; Platinum ions; Lanthanide contraction; Bond energies; Endothermic reactions; Transition metal ions; Dihydrogen2002
18 Armentrout, Peter B.Reactions of Ta+ and W+ with H2, D2, and HD: effect of lanthanide contraction and spin-orbit interactions on reactivity and thermochemistryA guided ion beam tandem mass spectrometer is used to examine the kinetic energy dependence of reactions of the third-row transition metal cations, Ta1, and W1, with molecular hydrogen and its isotopologs. A flow tube ion source produces Ta1 and W1 ions in their electronic ground state term and p...Metal clusters; Tantalum ions; Tungsten ions; Lanthanide contraction; Bond energies; Endothermic reactions; Transition metal ions; Dihydrogen2002
19 Armentrout, Peter B.Thermochemistry of the activation of N2 on iron cluster cations: guided ion beam studies of the reactions of Fen+ (n=1-19) with N2The kinetic energy dependences of the reactions of Fen + (n=1-19) with N2 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-15 eV. In addition to collision-induced dissociation forming Fem + ions, which dominate the product spectra, a variety of FemN2+ and FemN+ p...Metal clusters; Iron ions; Dinitrogen; Endothermic reactions; Collision-induced dissociation; Bond energies2006
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