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Filters: Collection: "ir_uspace" Subject: "Ion-molecule reactions"
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CreatorTitleDescriptionSubjectDate
1 Armentrout, Peter B.C+(2P) + H2(D2,HD)→CH+(CD+) + H(D). I. Reaction cross sections and kinetic isotope effects from threshold to 15 eV c.m.Total cross sections for the reactions of carbon (1 + ) ions with isotopic molecular hydrogen (H2, D2 , and HD) to form methyliumylidene (CH+ and C D + ) have been measured using guided ion beam techniques. Cross sections are reported as a function of the translational energy of the reactants fro...Ion-molecule reactions; Isotope effects; Translational energy; Threshold behavior; Endothermic reactions1986
2 Armentrout, Peter B.Dissociative charge transfer reactions of Ar+, Ne+, and He+ with CF4 from thermal to 50 eVGuided ion-beam techniques are used to measure the cross sections for reaction of CF4 with Ar+, Ne+, and H e + from thermal to 50 eV. Dissociative charge transfer followed by successive loss of F atoms are the major processes observed. Only CFx+ (x = 1,2,3) products are observed in the reactions of ...Ion-molecule reactions; Transfer reactions; Carbon tetrafluoride; Rare gas ions; Exothermic reactions; Endothermic reactions; Plasma systems1990
3 Armentrout, Peter B.Effect of kinetic and electronic energy on the reactions of Mn+ with H2, HD and D2Reactions of several electronic states of Mn+ with H2, HD, and D2 have been examined using guided ion beam mass spectroscopy. The excitation function for the ground state of Mn+ ( 75) has two regions: one of very low reactivity at threshold and another more efficient pathway at higher energies. In ...Ion-molecule reactions; Translational energy; Bond energy; Threshold behavior; Endothermic reactions; Metal ions; Manganese; Hydrogen1986
4 Armentrout, Peter B.Energetics and dynamics in the reaction of Si+ with SiF4. Thermochemistry of SiFx and SiFx+ (x=1,2,3)The title reaction is studied using guided ion beam mass spectrometry. Absolute reaction cross sections are measured as a function of kinetic energy from thermal to 40 eV, and three endothermic product channels are observed. The dominant SiF+ + SiF3 channel is only slightly endothermic, while the ...Silicon fluoride; Ion-molecule reactions; Kinetic energy; Threshold behavior; Endothermic reactions1988
5 Armentrout, Peter B.Energy dependence, kinetic isotope effects, and thermochemistry of the nearly thermoneutral reactions of N+(3P) + H2(HD, D2) → NH+(ND+) + H(D)The reactions of N + (3P) ions with H2 , HD, D2 are examined using guided ion beam tandem mass spectroscopy. Absolute reaction cross sections are measured from near thermal energies to 30 eV relative energy. The low energy cross section behavior is analyzed using empirical threshold models and ph...Thermoneutral reactions; Ion-molecule reactions; Translational energy; Bond energy; Threshold behavior; Phase space theory1987
6 Armentrout, Peter B.Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HDThe hydrogen atom transfer reactions of helium (1 +) and neon(1+) ions with isotopic molecular hydrogen (H2 , D2 , and HD) are investigated using guided ion beam techniques. These reactions are exothermic, but are known to be extremely slow at thermal energies. The cross sections for formation of...Transfer reactions; Ion-molecule reactions; Exothermic reactions; Hydrogen; Helium ions; Neon ions; Threshold behavior; Isotope effects1987
7 Armentrout, Peter B.Kinetic energy dependence of Al+ + O2→AlO+ + OThe endothermic reaction of Al+ with O2 is studied using a guided ion-beam apparatus. The reaction cross section is measured as a function of kinetic energy from 0 to 20 eV. The threshold energy for the reaction, E0, is determined from an empirical model to be 3.64 ± 0.04 eV.Ion-molecule reactions; Translational energy; Threshold behavior; Endothermic reactions; Aluminum; Oxygen1986
8 Armentrout, Peter B.Kinetic energy dependence of dissociative charge-transfer reactions of He+, Ne+, Ar+, Kr+, and Xe+ with silaneGuided ion-beam techniques are used to measure the cross sections as a function of kinetic energy for reaction of SiH4 with He +, Ne +, Ar +, Kr +, and Xe +. State-specific data for the 2P3/2 ground spin-orbit states of Kr+ and Xe+ are also obtained.Silane; Charge-transfer reactions; Ion-molecule reactions; Ion energy; Rare gas ions; Plasma systems1990
9 Armentrout, Peter B.Reactions of Ar+, Ne+, and He+ with SiF4 from thermal energy to 50 eV c.m.Guided ion-beam techniques are used to measure the cross sections for reaction of SiF4 with Ar+, Ne+, and He+ from thermal to 50 eV. Charge transfer followed by loss of F atoms are the sole processes observed. All SiFx + (x = 0-4) products are observed, except for SiF4 + from reaction with Ne+ and ...Ion-molecule reactions; Tetrafluorosilane; Rare gas ions; Endothermic reactions; Plasma systems1989
10 Armentrout, Peter B.Spin-orbit state-selected reactions of Kr+(2P3/2 and 2P1/2) with H2, D2, and HD from thermal energies to 20 eV c.m.Spin-orbit state-selected reactions of K r + (2Pj), J = 3/2 and / = 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form KrH+ and Kr D+ are investigated using guided ion beam techniques. Reaction cross sections for each spin-orbit state are measured as a function of the relative trans...Spin-orbit; Krypton ions; Hydrogen isotopes; Isotope effects; Potential energy surfaces; Ion-molecule reactions1986
11 Armentrout, Peter B.Spin-orbit state-selected reactions of Xe+(2P3/2 and 2P1/2) with H2, D2, and HDSpin-orbit state-selected reactions of X e + (2Pj ), j = 3/2 and 1/2, with isotopic molecular hydrogen (H2 , D2 , and HD) to form X e H + and XeD + are studied using guided ion beam mass spectrometry. Reaction cross sections are determined as a function of reactant kinetic energy from near thermal ...Spin-orbit; Xenon ions; Hydrogen isotopes; Isotope effects; Ion-molecule reactions1989
12 Armentrout, Peter B.Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m.Cross sections for the reactions of Ar+ with H2, D2, and HD to form ArH + and ArD + are measured using a new guided ion beam tandem mass spectrometer which affords an experimental energy range from 0.05 to 500 eV laboratory. The apparatus and experimental techniques are described in detail. Cross se...Translational energy; Ion-molecule reactions; Ion energy; Argon; Hydrogen; Endothermic reactions1985
13 Armentrout, Peter B.Translational energy dependence of O+(4S) + N2 → NO+ + N from thermal energies to 30 eV c.m.Guided ion beam mass spectrometry is used to examine the kinetic energy dependence of the reaction of ground state atomic oxygen ion with molecular nitrogen. An 0 + (4S) source which produces less than 0.06% excited states is described. Cross sections for the NO+ + N product channel decrease with...Ion-molecule reactions; Translational energy; Threshold behavior; Endothermic reactions; Nitrogen; Oxygen1987
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