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Creator | Title | Description | Subject | Date |
1 |
 | Minteer, Shelley D. | Nickel cysteine complexes as anodic electrocatalysts for fuel cells | Compared to platinum, nickel is an inexpensive catalyst that can oxidize methanol in alkaline media. There is a desire to increase nickel loading during electrodeposition for improved performance. In this paper, a nickel cysteine complex (NiCys) is used as the precursor for electrodeposition on glas... | | 2014-01-01 |
2 |
 | Minteer, Shelley D. | Nickel-DNA complexes: bioelectrocatalysis or not? | Alkaline fuel cells (AFC) are low temperature, quick-to-start devices that can achieve 50% operating efficiency. Low cost alternatives to platinum group electrocatalysts, which allow for direct reformation are desired. Nickel electrocatalysts are highly active in alkaline for the oxidation of fuels.... | | 2013-01-01 |
3 |
 | Minteer, Shelley D. | Photobioelectrochemistry: Solar energy conversion and biofuel production with photosynthetic catalysts | Photobioelectrochemical cells are devices which have been developed over the past few decades and use photosynthetic catalysts for solar energy conversion or biofuel production. In this paper, a critical review of reported photobioelectrochemical systems is presented. The systems discussed include s... | | 2014-01-01 |
4 |
 | Bohs, Lynn A. | Phylogeny of the carolinense clade of solanum (Solanaceae) inferred from nuclear and plastid DNA sequences | The large and economically important genus Solanum contains ca. 1,400 species distributed worldwide. One of the 12-14 major clades identified in the genus is the Leptostemonum clade, or the "spiny solanums." Previous molecular phylogenetic studies have identified 14 major clades in the spiny solanum... | | 2014-01-01 |
5 |
 | Mishchenko, Eugene | Resonant finite-size impurities in graphene, unitary limit, and Friedel oscillations | A unitary limit for model point scatterers in graphene is known to reveal low-energy resonances. The same limit could be achieved from hybridization of band electrons with the localized impurity level positioned in the vicinity of the Fermi level. The finite-size defects represent an easier realizat... | | 2012-01-01 |
6 |
 | Adler, Frederick R. | Reply: | We appreciate the comments of Drs. Craig and Simpson and Drs. Mullins and Schwartz, and the challenge they raise to make MALD more believable, comprehensible, and usable. Acetaminophen (APAP) toxicity is indeed a complex process involving multiple steps. Although the underlying mathematics is more i... | | 2012-01-01 |
7 |
 | Armentrout, Peter B. | The simplest b2+ ion: determining its structure from its energetics by a direct comparison of the threshold collision-induced dissociation of protonated oxazolone and diketopiperazine | Energy-resolved collision-induced dissociation of b2 + ions derived from protonated GGG and GAG are compared with that of protonated diketopiperazine (H+DKP). Absolute dissociation cross sections are obtained using a guided ion beam tandem mass spectrometer and analyzed using statistical methods. Th... | | 2012-01-01 |
8 |
 | Gondolo, Paolo | Simple renormalizable flavor symmetry for neutrino oscillations | The recent measurement of a nonzero neutrino mixing angle θ13 requires a modification of the tri-bimaximal mixing pattern that predicts a zero value for it. We propose a new neutrino mixing pattern based on a spontaneously broken A4 flavor symmetry and a type-I seesaw mechanism. Our model allows fo... | | 2012-01-01 |
9 |
 | Minteer, Shelley D. | Utilizing DNA for electrocatalysis: DNA-Nickel aggregates as anodic electrocatalysts for methanol, ethanol, glycerol, and glucose | DNA-nickel aggregates were electrodeposited onto glassy carbon electrode surfaces and have shown electrocatalytic activity for oxidation of methanol, ethanol, glycerol, and glucose at room temperature in alkaline solutions. Bulk electrolysis oxidation products identified by 13C NMR include carbonate... | | 2013-01-01 |
10 |
 | Capecchi, Mario R. | Modeling alveolar soft part sarcomagenesis in the mouse: a role for lactate in the tumor microenvironment | Alveolar soft part sarcoma (ASPS), a deadly soft tissue malignancy with a predilection for adolescents and young adults, associates consistently with t(X;17) translocations that generate the fusion gene ASPSCR1-TFE3. We proved the oncogenic capacity of this fusion gene by driving sarcomagenesis in m... | | 2014-01-01 |
11 |
 | Olivera, Baldomero M. | Modulation of conotoxin structure and function is achieved through a multienzyme complex in the venom glands of cone snails | Background: Conotoxins can be utilized to investigate enzyme-assisted folding of disulfide-rich peptides. Results: Various ER-resident cone snail enzymes act in concert to accelerate the oxidative folding of conotoxins and modulate their conformation by reconfiguring disulfide connectivities. Conclu... | | 2012-01-01 |
12 |
 | Parkinson, John Stansfield | Mutational analysis of the P1 phosphorylation domain in E. coli CheA, the signaling kinase for chemotaxis | The histidine autokinase CheA functions as the central processing unit in the Escherichia coli chemotaxis signaling machinery. CheA receives autophosphorylation control inputs from chemoreceptors and in turn regulates the flux of signaling phosphates to the CheY and CheB response regulator proteins... | | 2014-01-01 |
13 |
 | Jorgensen, Erik | Nano-fEM: Protein localization using photo-activated localization microscopy and electron microscopy | Mapping the distribution of proteins is essential for understanding the function of proteins in a cell. Fluorescence microscopy is extensively used for protein localization, but subcellular context is often absent in fluorescence images. Immuno-electron microscopy, on the other hand, can localize pr... | | 2012-01-01 |
14 |
 | Poulter, Charles Dale | Predicting the functions and specificity of triterpenoid synthases: a mechanism-based multi-intermediate docking approach | Terpenoid synthases construct the carbon skeletons of tens of thousands of natural products. To predict functions and specificity of triterpenoid synthases, a mechanism-based, multi-intermediate docking approach is proposed. In addition to enzyme function prediction, other potential applications of ... | | 2014-01-01 |
15 |
 | Mattis, Daniel C. | Preface | It was the early 1960s. Elliott H. Lieb and the present author were colleagues at the IBM Research Laboratories in Yorktown Heights, occupying neighboring cubicles. We collaborated in the study, creation and solution of mathematical models of many-body phenomena. In the course of this work we ultima... | | 2012-01-01 |
16 |
 | Capecchi, Mario R. | Sepp1UF forms are N-terminal selenoprotein P truncations that have peroxidase activity when coupled with thioredoxin reductase-1 | Mouse selenoprotein P (Sepp1) consists of an N-terminal domain (residues 1-239) that contains 1 selenocysteine (U) as residue 40 in a proposed redox-active motif (-UYLC-) and a Cterminal domain (residues 240-361) that contains 9 selenocysteines. Sepp1 transports selenium from the liver to other tiss... | | 2014-01-01 |
17 |
 | Farmer, Colleen G. | Unidirectional pulmonary airflow patterns in the savannah monitor lizard | The unidirectional airflow patterns in the lungs of birds have long been considered a unique and specialized trait associated with the oxygen demands of flying, their endothermic metabolism1 and unusual pulmonary architecture2,3. However, the discovery of similar flow patterns in the lungs of crocod... | | 2014-02-20 |
18 |
 | Armentrout, Peter B. | Thermodynamics and mechanisms of protonated diglycine decomposition: a computational study | We present a full computational description of the fragmentation reactions of protonated diglycine (H+GG). Relaxed potential energy surface scans performed at B3LYP/6-31G(d) or B3LYP/6-311+G(d,p) levels are used to map the reaction coordinate surfaces and identify the transition states (TSs) and int... | | 2012-01-01 |
19 |
 | Armentrout, Peter B. | Thermodynamics and mechanism of protonated cysteine decomposition: a guided ion beam and computational study | A quantitative molecular description of the decomposition of protonated cysteine, H+Cys, is provided by studying the kinetic energy dependence of threshold collision-induced dissociation (CID) with Xe using a guided ion beam tandem mass spectrometer (GIBMS). Primary dissociation channels are deamida... | | 2014-01-01 |
20 |
 | Armentrout, Peter B. | Thermodynamics and mechanisms of protonated diglycine decomposition: a guided ion beam study | We present a full molecular description of fragmentation reactions of protonated diglycine (H+GG) by studying their collision-induced dissociation (CID) with Xe using a guided ion beam tandem mass spectrometer (GIBMS). Analysis of the kinetic energy-dependent CID cross sections provides the 0 K barr... | | 2012-01-01 |
21 |
 | Poulter, Charles Dale | Tetartohedral twinning in IDI-2 from Thermus thermophilus: crystallization under anaerobic conditions | Type-2 isopentenyl diphosphate isomerase (IDI-2) is a key flavoprotein involved in the biosynthesis of isoprenoids. Since fully reduced flavin mononucleotide (FMNH2) is needed for activity, it was decided to crystallize the enzyme under anaerobic conditions in order to understand how this reduced co... | | 2014-01-01 |
22 |
 | Golden, Kenneth M. | Transition in the fractal geometry of Arctic melt ponds | During the Arctic melt season, the sea ice surface undergoes a remarkable transformation from vast expanses of snow covered ice to complex mosaics of ice and melt ponds. Sea ice albedo, a key parameter in climate modeling, is determined by the complex evolution of melt pond configurations. In fact, ... | | 2012-01-01 |
23 |
 | Bohs, Lynn A. | Two new species from the brevantherum clade of solanum (solanaceae) from eastern Brazil | Two new species of Solanum (Solanaceae) from eastern Brazil are described. Solanum anisocladum Giacomin & Stehmann is similar to S. megalochiton Mart., but differs by the indument of the adaxial leaf surface, which is composed of long porrect-stellate and unbranched trichomes. It also has a more rob... | | 2013-01-01 |
24 |
 | Jorgensen, Erik | UNC-41/stonin functions with AP2 to recycle synaptic vesicles in Caenorhabditis elegans | The recycling of synaptic vesicles requires the recovery of vesicle proteins and membrane. Members of the stonin protein family (Drosophila Stoned B, mammalian stonin 2) have been shown to link the synaptic vesicle protein synaptotagmin to the endocytic machinery. Here we characterize the unc-41 gen... | | 2012-01-01 |
25 |
 | Symko, Orest George | Ultrasonic thermoacoustic energy converter | Thermoacoustic prime movers have been developed for operation in the low ultrasonic frequency range by scaling down the device size. The developed engines operate at frequencies up to 23 kHz. They are self-sustained oscillators whose dimensions scale inversely with operating frequency. The smallest ... | | 2012-01-01 |