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| Creator | Title | Description | Subject | Date | ||
|---|---|---|---|---|---|---|
| 1 |
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Armentrout, Peter B. | Effect of kinetic and electronic energy on the reactions of Cr+ with H2, HD, and D2 | The reactions of atomic chromium ions with H2 , HD, and D2 are examined using guided ion beam tandem mass spectrometry. The ground electronic state (6S) is found to react inefficiently. The thresholds of these data are analyzed to yield a 0 K bond dissociation energy for CrH+ of 1.37 ± 0.09 eV (31... | Chromium ions; Hydrogen; Deuteride; Bond energy | 1987 |
| 2 |
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Armentrout, Peter B. | Effect of kinetic and electronic energy on the reactions of Mn+ with H2, HD and D2 | Reactions of several electronic states of Mn+ with H2, HD, and D2 have been examined using guided ion beam mass spectroscopy. The excitation function for the ground state of Mn+ ( 75) has two regions: one of very low reactivity at threshold and another more efficient pathway at higher energies. In ... | Ion-molecule reactions; Translational energy; Bond energy; Threshold behavior; Endothermic reactions; Metal ions; Manganese; Hydrogen | 1986 |
| 3 |
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Armentrout, Peter B. | Hydrogen atom transfer reactions of He+ and Ne+ with H2, D2, and HD | The hydrogen atom transfer reactions of helium (1 +) and neon(1+) ions with isotopic molecular hydrogen (H2 , D2 , and HD) are investigated using guided ion beam techniques. These reactions are exothermic, but are known to be extremely slow at thermal energies. The cross sections for formation of... | Transfer reactions; Ion-molecule reactions; Exothermic reactions; Hydrogen; Helium ions; Neon ions; Threshold behavior; Isotope effects | 1987 |
| 4 |
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Truong, Thanh | Reaction class transition state theory: hydrogen abstraction reactions by hydrogen atoms as test cases | We present a new method called Reaction Class Transition State Theory (RC-TST) for estimating thermal rate constants of a large number of reactions in a class. This method is based on the transition state theory framework within the reaction class approach. Thermal rate constants of a given reacti... | Transition state theory; Hydrogen | 2000 |
| 5 |
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Armentrout, Peter B. | Translational energy dependence of Ar+ + XY → ArX+ + Y (XY = H2, D2, HD) from thermal to 30 eV c.m. | Cross sections for the reactions of Ar+ with H2, D2, and HD to form ArH + and ArD + are measured using a new guided ion beam tandem mass spectrometer which affords an experimental energy range from 0.05 to 500 eV laboratory. The apparatus and experimental techniques are described in detail. Cross se... | Translational energy; Ion-molecule reactions; Ion energy; Argon; Hydrogen; Endothermic reactions | 1985 |
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