Publication Type |
pre-print |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Minteer, Shelley D. |
Other Author |
Milton, Ross D. |
Title |
Investigating the reversible inhibition model of laccase by hydrogen peroxide for bioelectrocatalytic applications |
Date |
2014-01-01 |
Description |
The reversible inhibition of laccase by H2O2 as a bioelectrocatalyst was studied in mediated- and direct electron transfer-based configurations to understand the differences in mechanism. The reversible inhibition of laccase follows a noncompetitive inhibition model when 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) is used as an electron mediator, whereas laccase is inhibited by an uncompetitive inhibition model when anthracene-moieties are used to intelligently "dock" laccase to electrodes (consisting of multi-walled carbon nanotubes, MWCNTs) which afford direct electron transfer (DET). This further confirms the efficient orientation of laccase onto suitably-designed docking moieties for bioelectrocatalysis applications. |
Type |
Text |
Publisher |
Electrochemical Society |
Volume |
161 |
Issue |
13 |
First Page |
H3011 |
Last Page |
H3014 |
Language |
eng |
Bibliographic Citation |
Milton, R. D., & Minteer, S. D. (2014). Investigating the reversible inhibition model of laccase by hydrogen peroxide for bioelectrocatalytic applications. Journal of the Electrochemical Society, 161(13), H3011-H4. |
Rights Management |
© The Electrochemical Society, Inc. 2014. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version of this work was published in [insert bibliographic information here]. |
Format Medium |
application/pdf |
Format Extent |
514,526 bytes |
Identifier |
uspace,19281 |
ARK |
ark:/87278/s6jt30j2 |
Setname |
ir_uspace |
ID |
712823 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6jt30j2 |