Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Heidecke, Scott A.; Fu, Zhenwen; Colt, John R.
Title Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit
Date 1992
Description Spectra of jet-cooled AlAr and AlKr have been collected over the range from 31 000 cm -? to the ionization limit, using the technique of resonant two-photon ionization spectroscopy with mass spectrometric detection. Adiabatic ionization potentials have been accurately measured for both molecules, and have been estimated for AlAr? and AlAr?. The spin-orbit splittings in the X ?II ground state have been determined for both AlAr and AlKr, and ground-state bond strengths have been accurately measured as Do [AlAr, Xi ?II1/2 (3p)] = 122.4 ? 4 cm-? and D?[27A1 84Kr, X, ?II1/2 (3p)] = 194.7 ? 0.8 cm-? . These values have also been combined with the measured ionization potentials to derive D?(Al+-Ar) = 982.3 ? 5 cm-? and D?(Al+-Kr) = 1528.5 ? 2cm- ?.
Type Text
Publisher American Institute of Physics (AIP)
Volume 97
Issue 3
First Page 1692
Last Page 1710
DOI 10.1063/1.463158
Language eng
Bibliographic Citation Heidecke, S. A., Fu, Z., Colt, J. R., & Morse, M. D. (1992). Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit. Journal of Chemical Physics, 97(3), 1692-710.
Rights Management ¬©American Institute of Physics. The following article appeared in Heidecke, S. A., Fu, Z., Colt, J. R., & Morse, M. D. (1992). Spectroscopy of AlAr and AlKr from 31 000 cm-1 to the ionization limit. Journal of Chemical Physics, 97(3), 1692-710. and may be found at http://dx.doi.org/10.1063/1.463158.
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Identifier ir-main,16994
ARK ark:/87278/s6514gs1
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Date Created 2012-06-13
Date Modified 2012-06-13
ID 706594
Reference URL https://collections.lib.utah.edu/ark:/87278/s6514gs1
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