Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Stang, Peter J. |
Other Author |
Seidel, S. Russell; Tabellion, Frank M.; Arif, Atta M. |
Title |
One-dimensional coordination polymers based on first-row transition metals: a solid-state study of weak backbone interactions |
Date |
2001 |
Description |
We present further data on the solid-state structures of one-dimensional coordination polymers based upon dipositive transition metal hexafluoroacetylacetonate (hfacac) complexes. A variety of linking subunits are employed in order to investigate and probe the relatively weak interactions that make up the backbones of these polymers. Reported in this study are metal complexes containing manganese, zinc, copper, and cobalt and a range of donor building blocks encompassing an array of bonding motifs, including pyridyl-metal, pyridyl(N-oxide)-metal, and hydrogen bonding. The specific linkers utilized are 4,4′-dipyridyl N,N′- dioxide hydrate, 2,5-bis(4-ethynylpyridyl)furan, 4,4′-trimethylenedipyridine, and trans-1-(2-pyridyl)-2-(4-pyridyl)-ethylene. A detailed discussion of the products is presented, as is a comparison to known compounds of a similar nature. All compounds are characterized via single-crystal X-ray diffraction and elemental analysis for the bulk of the sample. |
Type |
Text |
Publisher |
Laser Pages Publishing Ltd. |
Volume |
41 |
Issue |
3 |
First Page |
149 |
Last Page |
161 |
Subject |
Hexafluoroacetylacetonate complexes; Coordination polymers |
Subject LCSH |
Transition metal complexes; Polymers; Molecular structure |
Language |
eng |
Bibliographic Citation |
Seidel, S. R., Tabellion, F. M., Arif, A. M., & Stang, P. J. (2001). One-dimensional coordination polymers based on first-row transition metals: a solid-state study of weak backbone interactions. Israel Journal of Chemistry, 41(3), 149-61. |
Rights Management |
(c)Laser Pages Publishing Ltd. |
Format Medium |
application/pdf |
Format Extent |
673,075 bytes |
Identifier |
ir-main,9016 |
ARK |
ark:/87278/s6j39b3d |
Setname |
ir_uspace |
ID |
706241 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6j39b3d |