Photoinduced infrared activity in polyacetylene

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Publication Type Journal Article
School or College College of Science
Department Physics
Creator Vardeny, Zeev Valentine
Other Author Orenstein, Joseph; Baker, G. L.
Title Photoinduced infrared activity in polyacetylene
Date 1983-06
Description Photoexcitation of trans - but not cis -polyacetylene, results in the appearance of strongly-ir-active local modes at 1370 and 1260 cm-1. This observation demonstrates that the photogeneration of self-localized charge carriers is unique to the trans isomer. In spite of their localization the kinetic mass of these photocarriers is small, Mc ≈ (1-2.5)m, a result which is in quantitative agreement with calculations based on single-chain models.
Type Text
Publisher American Physical Society
Journal Title Physical Review Letters
Volume 50
Issue 25
First Page 2032
Last Page 2035
DOI 10.1103/PhysRevLett.50.2032
citatation_issn 0031-9007
Subject Photoinduced infrared activity; Photoexcitation
Subject LCSH Polyacetylenes -- Optical properties
Language eng
Bibliographic Citation Vardeny, Z., Orenstein, J., & Baker, G. L. (1983). Photoinduced infrared activity in polyacetylene. Physical Reveiw Letters, 50(25), June, 2032-5.
Rights Management (c) American Physical Society http://dx.doi.org/10.1103/PhysRevLett.50.2032
Format Medium application/pdf
Format Extent 360,673 bytes
Identifier ir-main,9573
ARK ark:/87278/s6mc9hjp
Setname ir_uspace
ID 706163
Reference URL https://collections.lib.utah.edu/ark:/87278/s6mc9hjp
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