The ?IIou ?X ???g band system of jet-cooled Ti?

Update item information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Morse, Michael David
Other Author Doverstal, Mats; Lindgren, Bo; Sassenberg, Ulf; Arrington, Caleb A.
Title The ?IIou ?X ???g band system of jet-cooled Ti?
Date 1992
Description A band of jet-cooled ??Ti? has been located in the near infrared by resonant two-photon ionization spectroscopy. Rotational analysis has shown the band to be an ?? =O* ???=1 transition, which is consistent with the 3??g, ground state proposed by Bauschlicher ef al. [J. Chem. Phys. 95, 1057 ( 1991)]. The band is assigned as a 3II0u ? X 3??g, transition, tnd lower and upper state bond lengths have been determined as r0(X 3?g) = 1.9422?0.0008 ? and rO( 31u,) = 1.997 ? 0.009 ? (l? error limits, corrected for spin-uncoupling effects). Comparisons are made to the TN and V, molecules, a rationale for the unusual filling order of the 3d-based molecular orbitals is provided, and molecular orbital assignments are considered for the excited 3IIu state.
Type Text
Publisher American Institute of Physics (AIP)
Volume 97
Issue 10
First Page 7087
Last Page 7092
DOI 10.1063/1.463534
Language eng
Bibliographic Citation Doverstal, M., Lindgren, B., Sassenberg, U., Arrington, C. A., & Morse M. D. (1992). The ?IIou ?X ???g band system of jet-cooled Ti?. Journal of Chemical Physics, 97(10), 7087-92.
Rights Management ¬©American Institute of Physics. The following article appeared in Doverstal, M., Lindgren, B., Sassenberg, U., Arrington, C. A., & Morse M. D. (1992). The ?IIou ?X ???g band system of jet-cooled Ti?. Journal of Chemical Physics, 97(10), 7087-92. and may be found at http://dx.doi.org/10.1063/1.463534.
Format Medium application/pdf
Format Extent 814,565 bytes
Identifier ir-main,16999
ARK ark:/87278/s6hx1x58
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 705885
Reference URL https://collections.lib.utah.edu/ark:/87278/s6hx1x58
Back to Search Results