Activation of methane by size-elected iron cluster cations, Fen+ (n=2-15): cluster-CHx (x=0-3) bond energies and reaction mechanisms

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Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Armentrout, Peter B.
Other Author Liyanage, Rohana; Zhang, Xiao-Guang
Title Activation of methane by size-elected iron cluster cations, Fen+ (n=2-15): cluster-CHx (x=0-3) bond energies and reaction mechanisms
Date 2001
Description The kinetic energy dependences of the reactions of Fen + (n=2 - 15) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. All reactions exhibit thresholds and two main products, FenD+ and FenCD2+, are formed.
Type Text
Publisher American Institute of Physics (AIP)
Journal Title The Journal of Chemical Physics
Volume 115
Issue 21
First Page 9747
Last Page 9763
DOI 10.1063/1.1413983
citatation_issn 219606
Subject Metal clusters; Iron ions; Bond energies; Dehydrogenation; Endothermic reactions; Transition metal ions
Subject LCSH Thermochemistry; Excited state chemistry; Iron; Methane
Language eng
Bibliographic Citation Liyanage, R., Zhang, X.-G., & Armentrout, P. B. (2001). Activation of methane by size-elected iron cluster cations, Fen+ (n=2-15): cluster-CHx (x=0-3) bond energies and reaction mechanisms. Journal of Chemical Physics, 115(21), 9747-63.
Rights Management (c)American Institute of Physics. The following article appeared in Liyanage, R., Zhang, X.-G., & Armentrout, P. B., Journal of Chemical Physics, 115(21), 2001 and may be found at http://dx.doi.org/10.1063/1.1413983
Format Medium application/pdf
Format Extent 25,606 bytes
Identifier ir-main,8041
ARK ark:/87278/s6st878f
Setname ir_uspace
Date Created 2012-06-13
Date Modified 2012-06-13
ID 705410
Reference URL https://collections.lib.utah.edu/ark:/87278/s6st878f
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