Publication Type |
Journal Article |
School or College |
College of Science |
Department |
Chemistry |
Creator |
Armentrout, Peter B. |
Other Author |
Liyanage, Rohana; Griffin, James B. |
Title |
Thermodynamics of ammonia activation by iron cluster cations: guided ion beam studies of the reactions of Fen+ (n=2-10,14) with ND3 |
Date |
2003 |
Description |
The kinetic energy dependences of the reactions of Fen 1 (n52 - 10,14) with ND3 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. Dehydrogenation of ammonia to form FenND1 is found to be efficient and exothermic for n54 in agreement with previous FT-ICR studies. In contrast to the ICR studies, we also observe exothermic dehydrogenation for n=3 and 5, although these processes are much less efficient than for n=4. Other clusters also undergo this process but exhibit an energy threshold. |
Type |
Text |
Publisher |
American Institute of Physics (AIP) |
Journal Title |
The Journal of Chemical Physics |
Volume |
119 |
Issue |
17 |
First Page |
8979 |
Last Page |
8995 |
DOI |
10.1063/1.1614753 |
citatation_issn |
219606 |
Language |
eng |
Bibliographic Citation |
Liyanage, R., Griffin, J. B., & Armentrout, P. B. (2003). Thermodynamics of ammonia activation by iron cluster cations: guided ion beam studies of the reactions of Fen+ (n=2-10,14) with ND3. Journal of Chemical Physics, 119(17), 8979-95. |
Rights Management |
(c)American Institute of Physics. The following article appeared in Liyanage, R., Griffin, J. B., & Armentrout, P. B., Journal of Chemical Physics, 119(17), 2003 and may be found at http://dx.doi.org/10.1063/1.1614753 |
Format Medium |
application/pdf |
Format Extent |
22,887 bytes |
Identifier |
ir-main,8014 |
ARK |
ark:/87278/s6j96qrd |
Setname |
ir_uspace |
ID |
704857 |
Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6j96qrd |