Spin crossover behavior of [FeII(isoxazole)6][BF4]2--a structural study

Update Item Information
Publication Type Journal Article
School or College College of Science
Department Chemistry
Creator Miller, Joel Steven
Other Author Hibbs, Wendy; Arif, Atta M.; van Koningsbruggen, Petra J.
Title Spin crossover behavior of [FeII(isoxazole)6][BF4]2--a structural study
Date 1999
Description [FeII(isoxazole)6][BF4]2 undergoes two reversible spin crossover transitions at 91 and 192 K and the single crystal structure determination reveals two different iron sites, Fe1 and Fe2, in a 1 : 2 ratio, with Fe1 attributed to the 91 K transition, and Fe2 attributed to the 192 K transition. This is the first such assignment for a material undergoing a two-step spin transition.
Type Text
Publisher Royal Society of Chemistry
Subject Transition; Magnetic; Temperature
Language eng
Bibliographic Citation Hibbs, W., Arif, A. M., van Koningsbruggen, P. J., & Miller, J. S. (1999). Spin crossover behavior of [FeII(isoxazole)6][BF4]2--a structural study. CrystEngComm, 4.
Rights Management (c)Royal Society of Chemistry
Format Medium application/pdf
Format Extent 64,471 bytes
Identifier ir-main,5626
ARK ark:/87278/s66t151j
Setname ir_uspace
ID 704699
Reference URL https://collections.lib.utah.edu/ark:/87278/s66t151j
Back to Search Results