| Publication Type |
Journal Article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Armentrout, Peter B. |
| Other Author |
Liu, Fuyi; Zhang, Xiao-Guang; Liyanage, Rohana |
| Title |
Methane activation by nickel cluster cations, Nin+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexes |
| Date |
2004 |
| Description |
The kinetic energy dependences of the reactions of Nin+ (n=2-16) with CD4 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-10 eV. The main products are hydride formation NinD1, dehydrogenation to form NinCD2 1 , and double dehydrogenation yielding NinC1. |
| Type |
Text |
| Publisher |
American Institute of Physics (AIP) |
| Journal Title |
The Journal of Chemical Physics |
| Volume |
121 |
| Issue |
22 |
| First Page |
10976 |
| Last Page |
16 |
| DOI |
10.1063/1.1814095 |
| citatation_issn |
219606 |
| Subject |
Nickel ions; Metal clusters; Deuterated methane; Collision-induced dissociation; Endothermic reactions; Bond energies; Dehydrogenation |
| Subject LCSH |
Methane; Transition metal ions; Catalysis; Thermochemistry; Excited state chemistry; Surface chemistry; Deuterium |
| Language |
eng |
| Bibliographic Citation |
Liu, F., Zhang, X.-G., Liyanage, R., & Armentrout, P. B. (2004). Methane activation by nickel cluster cations, Nin+ (n=2-16): reaction mechanisms and thermochemistry of cluster-CHx (x=0-3) complexes. Journal of Chemical Physics, 121(22), no. 15, 10976-90. |
| Rights Management |
(c)American Institute of Physics. The following article appeared in Liu, F., Zhang, X.-G., Liyanage, R., & Armentrout, P. B., Journal of Chemical Physics, 121(22), 2004 and may be found at http://dx.doi.org/10.1063/1.1814095 |
| Format Medium |
application/pdf |
| Format Extent |
31,030 bytes |
| Identifier |
ir-main,8000 |
| ARK |
ark:/87278/s6cr6bqb |
| Setname |
ir_uspace |
| ID |
704628 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6cr6bqb |
