| Publication Type |
journal article |
| School or College |
College of Science |
| Department |
Chemistry |
| Creator |
Miller, Joel Steven |
| Other Author |
Min, Kil Sik; Swierczek, Krzysztof; DiPasquale, Antonio G.; Rheingold, Arnold L.; Reiff, William M.; Arif, Atta M. |
| Title |
Dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange |
| Date |
2008 |
| Description |
Dinuclear [(TPyA)FeII(THBQ22)FeII(TPyA)](BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and p-p interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250 K with thermal hysteresis and ferromagnetic interactions at low temperature. |
| Type |
Text |
| Publisher |
Royal Society of Chemistry |
| First Page |
317 |
| Last Page |
319 |
| Subject |
Dinuclear complexes |
| Subject LCSH |
Iron compounds; Hysteresis; Ferromagnetism; Magnetic materials; Hydrogen bonding; Transition metal complexes; Ligands |
| Language |
eng |
| Bibliographic Citation |
Min, K. S., Swierczek, K., DiPasquale, A. G., Rheingold, A. L., Reiff, W. M., Arif, A. M., & Miller, J. S. (2008). Dinuclear iron(II) complex, [(TPyA)FeII(THBQ 2-)FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ2- = 2,3,5,6-tetrahydroxy-1,4- benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange. Chemical Communications, 3, 317-9. |
| Rights Management |
©Royal Society of Chemistry |
| Format Medium |
application/pdf |
| Format Extent |
356,287 bytes |
| Identifier |
ir-main,7725 |
| ARK |
ark:/87278/s6k93rr0 |
| Setname |
ir_uspace |
| ID |
703501 |
| Reference URL |
https://collections.lib.utah.edu/ark:/87278/s6k93rr0 |
